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烯丙基异冰片基醚绿色合成研究(PDF)

《南京林业大学学报(自然科学版)》[ISSN:1000-2006/CN:32-1161/S]

Issue:
2012年06期
Page:
95-100
Column:
研究论文
publishdate:
2012-12-05

Article Info:/Info

Title:
Green synthesis of allyl isobornyl ether
Author(s):
WANG Shikang XU Xu LAN Lan FAN Yuanyuan WANG Shifa*
Jiangsu Key Lab of Biomass Based Green Fuels and Chemicals,College of Chemical Engineering,  Nanjing Forestry University, Nanjing 210037, China
Keywords:
camphene allyl alcohol etherification allyl isobornyl ether
Classification number :
O62354
DOI:
10.3969/j.jssn.1000-2006.2012.06.019
Document Code:
A
Abstract:
Green synthetic method of allyl isobornyl ether was investigated by using camphene and allyl alcohol as the raw materials in this paper. Influence of catalysts and their usages, reaction temperature, reaction time, and the molar ratio of allyl alcohol to camphene on the selectivity of etherification and the yield of allyl isobornyl ether were examined, and the optimum synthesis conditions were determined based on the orthogonal test results as follows: A15 resin was used as the catalyst for etherification, and the amount of A15 cationic exchange resin was 5 % (based on the total weight of camphene and allyl alcohol); molar ratio of allyl alcohol to camphene was 15〖DK〗∶1; reaction temperature and reaction time were 75 ℃ and 7 h, respectively. The conversion ratio of camphene and the reaction selectivity reached 855 % and 975 % respectively, and the yield of allyl isobornyl ether also reached 834 %. The structure of allyl isobornyl ether was identified by GCMS and IR spectra.

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Last Update: 2012-11-30