微波辐射下莰烯与乙醇的加成反应

林中祥;顾阳

南京林业大学学报(自然科学版) ›› 2001, Vol. 25 ›› Issue (05) : 21-24.

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南京林业大学学报(自然科学版) ›› 2001, Vol. 25 ›› Issue (05) : 21-24. DOI: 10.3969/j.jssn.1000-2006.2001.05.005
研究论文

微波辐射下莰烯与乙醇的加成反应

  • 林中祥;顾阳
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The Reaction of Camphene with Ethyl Alcohol under Microwave Irradiation

  • LIN Zhong-xiang , GU Yang
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摘要

<正>研究了在微波辐射下莰烯与乙醇加成生成异菠基乙醚的反应。莰烯、乙醇、对甲苯磺酸的混合物在微波辐射下反应 30min ,可使反应液中异菠基乙醚的质量分数达 76.35 % ,反应速率比加热回流条件下的反应提高了十几倍。

Abstract

The reaction of camphene with ethyl alcohol to gi ve isobornyl ethyl ether under microwave irradiation was studied. The content of isobornyl ethyl ether in the reaction mixture reached 76.35% in the presence of p-toluene-sulfonic acid under microwave irradiation for 30 min at atmospheric pressure.The rate of reaction under microwave irradiation was over ten times hi gher than that under reflux.

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林中祥;顾阳. 微波辐射下莰烯与乙醇的加成反应[J]. 南京林业大学学报(自然科学版). 2001, 25(05): 21-24 https://doi.org/10.3969/j.jssn.1000-2006.2001.05.005
LIN Zhong-xiang , GU Yang. The Reaction of Camphene with Ethyl Alcohol under Microwave Irradiation[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2001, 25(05): 21-24 https://doi.org/10.3969/j.jssn.1000-2006.2001.05.005
中图分类号: TQ655   

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