D, L-乳酸的立构选择性聚合

高勤卫1,李明子2,董晓1

南京林业大学学报(自然科学版) ›› 2008, Vol. 32 ›› Issue (03) : 43-47.

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南京林业大学学报(自然科学版) ›› 2008, Vol. 32 ›› Issue (03) : 43-47. DOI: 10.3969/j.jssn.1000-2006.2008.03.010
研究论文

D, L-乳酸的立构选择性聚合

  • 高勤卫1,李明子2,董晓1
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Stereoselective polymerization of D, L-lactic acid

  • GAO Qin-wei1, LI Ming-zi2, DONG Xiao1
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摘要

<正>通过对湿加松(湿地松×洪都拉斯加勒比松)家系间早晚生长性状的相关性研究表明,18个湿加松家系的树高、胸径、材积差异均极显著;各家系树高、胸径、材积的年度相关主要受遗传影响;造林后第2年的树高、第3年的胸径和材积估计造林后10a的材积均具有极显著的相关性,而且选择效率最高,表明湿加松家系在造林后2a可进行早期选择。湿加松早期选择的方法是:在2年生时根据树高生长量淘汰早期生长较差的家系,淘汰率为30%以内;在6年生时根据材积生长量选择生长最优的家系,入选率为35%r以内。

Abstract

D, L-lactic acid was polymerized through melt polycondesation in order to prepare poly(lactic acid) with high optical properly. Polarimetry, FT-1R, DSC, 1H-and 13C-NMR were used to detect microstructure, molecular weight, and optical purity of poly (lactic acid) samples. Racemic PDLLA was prepared from D,L-lactic acid with Sn powder as catalyst or without catalyst. Both SnCl2/p-toluenesulfonic acid system and SnCl2/o-toluenesulfonic acid systern could be used as catalyst to obtain PDLLA with higher molecular weight(M,>20 000), lower dispersity (being 1. 1), and higher optical purity (70. 5%) due to excessive L-conformation units in polymer chain. Poly(lactic acid) with high optical purity prepared from D, L-lactic acid could effectively low the cost of poly(lctic acid) materials.

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高勤卫1,李明子2,董晓1. D, L-乳酸的立构选择性聚合[J]. 南京林业大学学报(自然科学版). 2008, 32(03): 43-47 https://doi.org/10.3969/j.jssn.1000-2006.2008.03.010
GAO Qin-wei1, LI Ming-zi2, DONG Xiao1. Stereoselective polymerization of D, L-lactic acid[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2008, 32(03): 43-47 https://doi.org/10.3969/j.jssn.1000-2006.2008.03.010
中图分类号: O633.14   

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