为优化紫外光固化弹性地板漆的涂装工艺,笔者研究了由4种油漆构成的7种涂层结构对漆膜拉伸强度、硬度、附着力、耐磨性等参数的影响。结果表明:在相同的涂布量和固化条件下,涂层的构成和结构对紫外光固化漆膜的硬度、耐磨性、附着力和拉伸强度都有比较明显的影响。采用紫外光固化漆解决地板的开裂问题时,3层弹性底漆和2层耐磨面漆的复合涂层结构效果较好,此时地板漆的硬度达到3H,100 r磨耗值低于0.09 g,附着力等级达到ISO标准1级,最大拉断伸长率达到6.88%且无裂纹。
Abstract
In this paper, the effects of seven coating structures formed by four types of paints on the performance of coating film, including tensile strength, hardness, adhesion and wearing resistance were investigated for optimizing the process conditions of UV(Ultraviolet)curing elastic flooring paint. The results showed that the composition and structure of the coating had obvious influence on the performance, including hardness, wearing resistance, adhesion and tensile strength of UV curing elastic coating film under the same dosage and curing condition. The composite coating structures of three UV high-elastic undercoat layers and two UV wear-resisting finishing coat layers were most effective to solve the problem of floor cracking with 3H hardness, 100 r wearing value<0.09 g, grade 1 ISO level adhesion, elongation at break 6.88% without film cracking.
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] Wang K. Practical of wood industry: furniture of securities [M]. Beijing: China Forestry Publishing House, 1998.
王恺.木材工业实用大全:家具卷[M]. 北京:中国林业出版社,1998.
[2] Yang Q Y. Wood paint film surface defects and countermeasures [J]. China Paint, 1999(5): 32-36.
杨其岳. 木器漆膜表面状态缺陷及解决对策[J]. 中国涂料,1999(5):32-36.
[3] Wang D H, Zhu Q, Hu Z Y, et al. Use of water-borne woodenware coatings in industrial application [J]. China Coatings, 2011(7): 51-54.
王德华,朱强,胡中源,等. 水性木器涂料在工业涂装中的应用[J]. 中国涂料,2011(7):51-54.
[4] Yang J W, Zeng Z H, Chen Y L. UV curing coatings and application [M]. Beijing: Chemical Industry Press, 2011: 82.
杨建文,曾兆华,陈用烈. 光固化涂料及应用[M]. 北京:化学工业出版社,2011:82.
[5] Shen X F, Gu B, Gou X Q. Application of UV-cured coatings in architectural decorative materials [J]. Coatings Technology & Abstracts, 2012(10): 29-31.
沈雪锋,顾斌,苟小青. 紫外光固化涂料在建筑装饰板上的应用[J]. 涂料技术与文摘,2012(10):29-31.
[6] Yao Y P, Cui Y Y, Dong Z X, et al. Progress of waterborne UV-curable coatings [J]. Paint Industry, 2011, 41(8):74-79.
姚永平,崔艳艳,董智贤,等. 水性光固化涂料研究进展[J]. 涂料工业,2011,41(8):74-79.
[7] Lu Z G, Shen L M, Huang H L, et al. Influence of coatings coverage of waterborne furniture coatings on abrasion resistance of film [J]. Paint and Coatings Industry, 2007, 37(3): 56-58.
路则光,申利明,黄河浪,等. 木器用水性涂料涂布量对漆膜耐磨性的影响[J]. 涂料工业,2007,37(3):56-58.
[8] Visconti M. Difunctional photoinitiators [M]. Trivandrum: Photochemistry and Photobiology Research Signpost, 2006.
[9] Xiao P, Wang Y, Dai M Z,et al.Synthesis and photopolymerization kinetics of benzophenone piperazine one-component initiator [J]. Polymers for Advanced Technologies, 2008, 19(5): 409-413.
[10] Sun W S, Jiang J, Shen B H, et al. Abrasion resistance of solid wood flooring with elastic coating [J]. Wood Industry, 2011, 25(2): 40-42.
孙伟圣,姜俊,沈斌华,等. 新型弹性漆面实木地板漆膜耐磨性的测试[J]. 木材工业,2011,25(2):40-42.
[11] Yang C J, Jiang H W. Study on toughening of UV-curable epoxy acrylate system [J]. Applied Chemical Industry, 2011, 40(4): 652-654.
杨传景,姜宏伟. 光固化环氧丙烯酸酯体系的增韧研究[J]. 应用化工,2011,40(4):652-654.
[12] Holman R, Oldring P. UV & EB curing formulations for printing inks: coatings & paints [M]. London: Selective Industrial Training Associates Limited, 1984: 19-46.
[13] Schollenberger C S, Stewart F D. Thermoplastic urethane elastomer ultraviolet stabilization: influence of polymer structure and stabilizers [J]. Advances in Urethane Science and Technology, 1976(4): 68-88.
[14] Rodríguez R, Estevez M, Vargas S, et al. Hybrid ceramic-polymer material for wood coating with high wearing resistance [J]. Materials Research Innovations, 2003, 7(2): 80-84.
[15] Gisele B A, Tunja J R H. Surface-active siloxane photointiators: US, 7105582[P]. 2006-06-20.
基金
收稿日期:2015-03-13 修回日期:2015-05-19
基金项目:国家林业公益性行业科研专项项目(201304501)
第一作者:于家豪,硕士。*通信作者:徐建峰,助理研究员。E-mail: xujianfeng198216@aliyun.com。
引文格式:于家豪,龙玲,徐建峰,等. 涂层组成对紫外光固化弹性地板漆膜性能的影响[J]. 南京林业大学学报:自然科学版,2015,39(5):139-144.