响应面法优化中温固化酚醛树脂的制备

doi:10.3969/j.issn.1000-2006.2014.03.035

国家林草科技领军期刊
中国精品科技期刊
中国高校百佳科技期刊
江苏省新闻出版政府奖期刊奖
RCCSE林学权威期刊（A+）
CSCD核心期刊
Scopus数据库收录期刊
中文核心期刊
SCD核心期刊

作者加群：102861116

微信公众号：南京林业大学学报

高级检索

南京林业大学学报（自然科学版） ›› 2014, Vol. 38 ›› Issue (03): 179-183.doi: 10.3969/j.issn.1000-2006.2014.03.035

• 研究简报 • 上一篇

响应面法优化中温固化酚醛树脂的制备

黄剑峰^1,2,陈奶荣¹,林巧佳^1*,饶久平¹,曾钦志¹

1.福建农林大学材料工程学院,福建福州 350002;
2.中国建材检验认证集团厦门宏业有限公司,福建厦门 361000

出版日期:2014-05-15 发布日期:2014-05-15
基金资助:
收稿日期:2013-01-05 修回日期:2013-12-09
基金项目:国家自然科学基金项目(30972311); 福建省科技厅产学研重大专项基金项目(2010N5001); 福建省林业厅科学基金资助项目(闽林科201103-2)
第一作者:黄剑峰,硕士生。*通信作者:林巧佳,教授。E-mail:linqj208@163.com。
引文格式:黄剑峰,陈奶荣,林巧佳,等. 响应面法优化中温固化酚醛树脂的制备[J]. 南京林业大学学报:自然科学版,2014,38(3):179-183.

Optimization of preparation of mid-temperature curing phenol-formaldehyde resin by response surface methodology

HUANG Jianfeng^1,2, CHEN Nairong¹, LIN Qiaojia^1*,RAO Jiuping¹,ZENG Qinzhi¹

1.College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China;
2.China Building Material Test &
Certification Group Xiamen Hongye Co.,Ltd., Xiamen 361000, China

Online:2014-05-15 Published:2014-05-15

摘要/Abstract

摘要： 以尿素、间苯二酚为改性剂,在碱性条件下制备中温固化酚醛树脂。利用Design-Expert软件建立数学模型,以胶合强度为响应值,优化酚醛树脂的原料配比。结果表明,中温固化酚醛树脂原料的最佳配比为:甲醛与苯酚摩尔比为2.32,氢氧化钠与苯酚摩尔比0.56,尿素加量为苯酚质量的20.03%,间苯二酚加量为苯酚质量的9.98%。在此条件下制备的酚醛树脂可以在105～115 ℃下固化。

Abstract: Urea and resorcinol were used as modifiers to prepare mid-temperature curing phenol-formaldehyde resin(PF)in alkaline condition, and the response surface methodology was used to optimize the effects of raw materials ratio on bonding strength. The optimal raw materials ratio of PF were determined as follows: molar ratios of formaldehyde and alkali to phenol were 2.32 and 0.56, respectively; and the mass of urea and resorcinol to phenol were 20.03% and 9.98%, respectively. Under these raw materials ratio, the curing temperature of the PF was in the range of 105-115 ℃.

中图分类号:

TQ323.1

黄剑峰,陈奶荣,林巧佳,等. 响应面法优化中温固化酚醛树脂的制备[J]. 南京林业大学学报（自然科学版）, 2014, 38(03): 179-183.

HUANG Jianfeng, CHEN Nairong, LIN Qiaojia,RAO Jiuping,ZENG Qinzhi. Optimization of preparation of mid-temperature curing phenol-formaldehyde resin by response surface methodology[J].Journal of Nanjing Forestry University (Natural Science Edition), 2014, 38(03): 179-183.DOI: 10.3969/j.issn.1000-2006.2014.03.035.

参考文献

[1] 余先纯,孙德林,李湘苏.木材胶黏剂与胶合技术[M].北京:中国轻工业出版社,2011.
[2] 钱小瑜.我国人造板与板式家具共赢市场[J].中国人造板,2011(3):66-76.Qian X Y.A win-win market for panel industry and panel-type furniture industry in China[J]. China Wood-based Panels,2011(3):66-76.
[3] 张忠涛.我国木材工业用胶黏剂产业现状及发展趋势[J].林产工业,2011,38(3):7-9.Zhang Z T. Current situation and development trend of wood adhesive industry in China[J].China Forest Products Industry,2011,38(3):7-9.
[4] 顾继友.胶粘剂与涂料[M].北京:中国林业出版社,2008.
[5] 唐丽荣,欧文,林雯怡,等.酸水解制备纳米纤维素工艺条件的响应面优化[J].林产化学与工业,2011,31(6):61-65.Tang L R, Ou W,Lin W Y,et al.Optimization of acid hydrolysis processing of nanocellulose crystal using response surface methodology[J].Chemistry and Industry of Forest Products,2011,31(6):61-65.
[6] Filson P B,Dawson-Andoh B E. Sono-chemical preparation of cellulose nanocrystals from lignocelluloses derived materials[J].Bioresource Technology,2009,113(2):1270-1275.
[7] 王永贵,郭俊英,张晓露,等.响应面优化法研究蔗糖苯酚树脂胶粘剂的合成[J].化工新型材料,2011,39(1): 113-116.Wang Y G,Guo J Y, Zhang X L,et al.Optimization of synthesis of sucrose-phenol resin adhesive by response surface methodology[J].New Chemical Materials,2011,39(1):113-116.
[8] 孙静,尤毅,蒋发现,等.云芝菌株胞外多糖的制备及纯化[J].南京林业大学学报:自然科学版,2012,36(6):85-89.Sun J,You Y,Jiang F X, et al.Preparation and purification of extracellular polysaccharide from coriolus versicolor[J].Journal of Nanjing Forestry University:Natural Sciences Edition, 2012,36(6):85-89.
[9] 全国人造板标准化技术委员会. GB/T 9846.7—2004 胶合板第7部分:试件的锯制[S].北京:中国标准出版社,2004.
[10] 全国人造板标准化技术委员会. GB/T 17657—1999 人造板及饰面人造板理化性能试验方法[S].北京:中国标准出版社,1999.
[11] 黄剑峰.中温固化酚醛树脂的研制[D].福州:福建农林大学,2013.Huang J F.Preparation of mid-temperature curing phenol formaldehyde resin[D].Fuzhou: Fujian Agriculture and Forest University,2013.
[12] 江华,张洋,王雪飞,等.柱状假丝酵母脂肪酶去除麦秸中亲脂类抽提物的研究[J].南京林业大学学报:自然科学版,2012,36(2):35-41.Jiang H,Zhang Y,Wang X F,et al.Study on removal of lipophilic extractives from wheat straw by candida cylindracea lipases[J].Journal of Nanjing Forestry University:Natural Sciences Edition,2012,36(2):35-41.
[13] 史垠垠,石瑞,曹福亮.澄清白果汁酶解工艺的研究[J].南京林业大学学报:自然科学版,2010,34(3):11-14.Shi Y Y,Shi R,Cao F L.Research on the enzymolysis processing of clarified ginkgo juice[J]. Journal of Nanjing Forestry University:Natural Sciences Edition, 2010,34(3):11-14.
[14] 吴嘉恩,刘自力,彭斌,等.高羟甲基低游离醛含量甲阶酚醛树脂的合成[J].材料研究与应用,2010,4(4):473-479.Wu J E,Liu Z L,Peng B,et al.Synthesis of resole phenol-formaldehyde resin containing high methylol group and low free formaldehyde content[J].Materials Research and Application,2010,4(4):473-479.
[15] 时君友,韩忠军.尿素改性酚醛树脂胶粘剂的研究[J].粘接,2006,27(1):15-17.Shi J Y,Han Z J.Study on urea-modified phenol formaldehyde resin adhesive[J]. Adhesion,2006,27(1):15-17.
[16] 范东斌,刁艳,李建章,等.苯酚-尿素-甲醛共缩聚树脂结构与胶接性能关系研究[J].北京林业大学学报,2009,31(1):15-19.Fan D B,Diao Y,Li J Z,et al.Relationship between structure and bonding properties of phenol-urea-formaldehyde cocondensed resins[J].Journal of Beijing Forestry University,2009,31(1):15-19.
[17] 王春鹏,赵临五,刘奕,等.间苯二酚-苯酚-甲醛树脂制备及性能研究[J].林产化学与工业,1999,19(4):23-28.Wang C P,Zhao L W,Liu Y,et al.Study on the preparation and properties of resorcinol-phenol-formaldehyde resins[J].Chemistry and Industry of Forest Products,1999,19(4):23-28.
[18] 张一甫,甘卫星.共缩聚间苯二酚酚醛胶粘剂的合成研究[J].粘接,2002,23(1):19-21.Zhang Y F,Gan W X.Study on synthesis of a resorcinol Bakelite adhesive by condensation polymerization[J].Adhesion,2002,23(1):19-21.
[19] 张建辉,常丽娟.中温固化水溶性酚醛树脂胶的研究[J].林产工业,2005,32(4):26-28.Zhang J H,Chang L J.Study on mid-temperature curing water soluble PF resin[J].China Forest Products Industry,2005,32(4):26-28.
[20] 韩健.间苯二酚共聚PF树脂固化特性及应用效果的研究[J].中国胶粘剂,2005,14(8):5-8.Han J.Study on resorcinol to PF resin curing property and application effect[J].China Adhesives, 2005,14(8):5-8.
[21] 全国人造板标准化技术委员会. GB/T 9846.3—2004 胶合板第3部分:普通胶合板通用技术条件[S].北京:中国标准出版社,2004.

响应面法优化中温固化酚醛树脂的制备

Optimization of preparation of mid-temperature curing phenol-formaldehyde resin by response surface methodology

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价

作者

读者

审稿