南京林业大学学报(自然科学版) ›› 1983, Vol. 7 ›› Issue (01): 39-49.doi: 10.3969/j.jssn.1000-2006.1983.01.004

• 研究论文 • 上一篇    下一篇

意大利杨木制浆造纸性能的研究——硫酸盐-蒽醌法和烧碱-蒽醌法

李忠正;张大同;赵觉声;姚光裕;薛国新   

  1. 南京林产工业学院林化系;南京林产工业学院林化系;南京林产工业学院林化系;南京林产工业学院林化系;南京林产工业学院林化系
  • 出版日期:1983-03-18 发布日期:1983-02-18

STUDIES OF PULPING AND PAPERMAKING PROPERTIESOF ITALIAN POPLARS——SULFATE-ANTHRAQUINONE PROCESS AND SODA-ANTHRAQUINONE PROCESS

Li Zhongzheng, Zhang Datong, Zhao Juesheng, Yao Guangyu and Xue Guoxin   

  1. Department of Chemical Processing of Forest Products
  • Online:1983-03-18 Published:1983-02-18

摘要: <正> 目前,造纸原料已成为阻碍造纸工业发展的重要问题之一。这使得人们将注意力从针叶材逐渐转向阔叶材,转向速生杨树和桉树。在意大利杨木Ⅰ-214、Ⅰ-72、Ⅰ-63、Ⅰ-69的研究中,除Ⅰ-214得到有关国家的广泛引种和利用外,其他三种杨木作为造纸原料,仍处于试验阶段,而Ⅰ-214的利用在国外也仅限于制造机械浆和化学机械浆,化学浆的研究工作迄今尚无报道。我国从七十年代开始由国外引种了几种意大利杨,北京造纸所于一九七六年曾对最先引进的Ⅰ-214的制浆造纸性能进行了研究,证明Ⅰ-214杨为优良造纸用材,但对其他三种材种还缺乏系统深入的研究。 我们在对四种意大利杨的化学组成和纤维形态进行研究的基础上,着重进行了硫酸盐法、烧碱-蒽醌法、硫酸盐-蒽醌法和碱性亚硫酸盐法制取化学浆的试验研究,比较了四种速生杨木对制取化学浆的适应性。本文主要对烧碱-蒽醌法代替硫酸盐法的可能性和蒽醌在杨木硫酸盐法、烧碱法制浆中的作用以及四种意大利杨对碱法制浆的适应性进行了探讨。

Abstract: By sulfate-anthraquinone and soda-anthraquinone processes effects of ratioes of alkali and anthiaquinone to wood chips, cooking temperatures and durations on pulp yields and properties of four Italian poplars were studied. The test results and regression analyses indicate that the optimum process conditions for sulfate-anthraquinone cooking of Italian poplar chips are alkai (as Na2O)17%, anthraquinone 0.05%, ratio of liquor to chips 4:1, the highest temperature 165°C and the reaction duration 90 min., and the results obtained thereupon are a total pulp yield of 54.50% and a kappa number of 24.60. The optimum conditions for soda-anthraquinone process are alkalis 16%, anthraquinone 0.05%, ratio of liquor to chips 4:1, the highest temperature 165°C and the reaction duration 120 min, with a cooking result showing a a total pulp yield of 54.16% and a kappa number of 23.77. The test results show that the yields and Kappa numbers of pulp gained by soda-anthraquinone process and sulfate process are approximately the same. Bleaching properties and physical-mechanical strength of the pulps are also very similar. The pulping and papermaking properties of the four Italian poplars tested differ only very slightly, of which I-214 is the best, next comes I-69 and then I-72 and I-63. All of them can produce paper with proper strength, therefore, they are good raw material for pulping and paper-making.