南京林业大学学报(自然科学版) ›› 1983, Vol. 7 ›› Issue (04): 111-118.doi: 10.3969/j.jssn.1000-2006.1983.04.010

• 研究论文 • 上一篇    下一篇

用CZC提高意杨人造板的耐久性

陈荪云;尹思慈;王婉华   

  1. 南京林产工业学院林学系;南京林产工业学院林工系
  • 出版日期:1983-12-18 发布日期:1983-08-18

IMPROVEMENT OF THE DURABILITY OF ITALIAN POPLARS PLYWOOD AND ORIENTED FLAKEBOARD WITH CZC

Chen Sunyun(Department of Forestry)Yin Sici & Wang Wanhua   

  1. Department of Wood Science and Technology
  • Online:1983-12-18 Published:1983-08-18

摘要: <正> 我国森林资源有限,利用意杨发展胶合板生产具有较大的价值。意杨定向刨花板的制造,对提高木材利用率则有更大的作用。 根据木材的天然耐久性,Wilkinson把木材分成五级——显著耐久、耐久、中等耐久、耐久差和易腐蛀,并把杨木列入最低一级。所以,利用杨木制作人造板,除须了解其生产最佳工艺条件外,尚应研究提高它的耐久性。 近年来国外应用的四种主要耐水性盐类防腐剂是:CCA(铬化砷铜)、CZC(铬化氯化锌)FCAP(氟/铬/砷/酚)和ACC(铵化砷酸铜)。其中使用最多的是CCA。衡量木材防腐剂适用性的主要因素是,它对环境污染的大小、提高耐久性的程度、在木材中的持久性和处理费用的多少。五氧化二砷是CCA的主要成分之一,人们顾虑它具有致癌性。我国对CCA的配制和应用中的动物毒性测定尚乏研究。CZC也是目前国外采用的一种木材防腐剂,它能抗水淋失,并具防腐和滞火两种性能;它的成分对人毒性低,处理和使用中的安全可得到保障。因此本试验采用CZC作为处理剂。

Abstract: Natural durability of solid wood of Italian poplars is very low. Samples of 4 species-Populcs deltoides cv. "Harvard" (ex. 1-63/51). Populus euramericana cv. "San Martina" (ex. 1-72/58), Fraxinus mandshurica Rupr. and Tilia amanurensis Rupr. were subjected to wooddestroying fungus (Lenzites Irabea Pers. ex Fr.) for one andhalf months in the soil block test. In decay test, although the mean percent of weight loss of plywood and oriented flakeboard of poplars was slightly lower than wood, they were still perishable. They may be molded very easily. Therefore it is important to improve the durability of wood and wood products in the utilization of poplars.Composite boards of Italian poplars were treated with chromated zinc chloride (CZC). The effect of treatment was evident. The weight loss of poplars plywood and oriented flakeboard treated by impregnation with a 1.5g/l solution of the preservative for an hour and a half was lower than those of ash and bass wood. Dry salt retention of wood is about 6.5kg/m3 after treatment with a 3.0g/l solution, and 9.2kg/m3 with 4.5g/l solution. The former can be used in a severe fungus and/or insect attack condition and the latter even in more serious conditions.After impregnating for one and half hours, the moisture content of plywood was 42-45 percent, and oriented flakeboard 21-26 percent. The weight concentration of CZC is the main factor which determines the salt retention of treated wood, whereas the absorptivity and moisture content of wood are of minor importance.