摘要
<正>本文试图应用大π键理论及分子轨道理论探讨AB_3型无机分子的结构,阐明了至今一些不能解释的有关分子结构如几何构型、价电子数目等问题。 作者从NO_3~-分子的结构出发引伸讨论了有关AB_3型分子(如CO_3~(2-),SO_3,BF_3,BCl_3,BB_(r3)等)的分子轨道的一般规律。
Abstract
Using the large π bond theory and the molecular orbital theory, the inorganic molecular structure of AB3 type is tentatively explored. Some problems about the molecular structure such as the geometric shape and valency electronic number which have not yet been solved up to now are cleared up. Starting form the NO3- structure, the molecular orbital model of the AB3 type, including CO32-, SO3, BF3, BC13, BBr3, etc. is investigated.
黄剑朎.
AB_3型分子的大π键及其分子轨道[J]. 南京林业大学学报（自然科学版）. 1986, 10(04): 78-82 https://doi.org/10.3969/j.jssn.1000-2006.1986.04.010
Huang Jianling.
THE LARGE π BOND OF AB3 TYPE MOLECULES AND THEIR MOLECULAR ORBITALS[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 1986, 10(04): 78-82 https://doi.org/10.3969/j.jssn.1000-2006.1986.04.010
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
PDF(263625 KB)
