PVAc-NMA-Urea三元共聚乳液的稳定性和膜性能

崔会旺1,2,杜官本1

南京林业大学学报(自然科学版) ›› 2007, Vol. 31 ›› Issue (03) : 83-86.

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南京林业大学学报(自然科学版) ›› 2007, Vol. 31 ›› Issue (03) : 83-86. DOI: 10.3969/j.jssn.1000-2006.2007.03.017
研究论文

PVAc-NMA-Urea三元共聚乳液的稳定性和膜性能

  • 崔会旺1,2,杜官本1
作者信息 +

Study on Stability and Filming of Copolymerization Emulsion PVAc-NMA-Urea

  • CUI Hui-wang1,2, DU Guan ben1
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文章历史 +

摘要

<正>研究了腐殖质对重金属Cu2+和Pb2+的吸附特性。结果表明:腐殖质对Cu2+、Pb2+均具有较强的吸附性能,但存在着明显的差异,腐殖质对Pb2+的吸附能力远远大于Cu2+腐殖质对Cu2+的吸附用Langmuir方程拟合效果优于用Freundlich方程拟合效果,而两个方程对Pb2+吸附的拟合程度都较好。用Langmuir吸附等温式推测腐殖质对Cu2+、Pb2+的饱和吸附量,分别为13.09mg/g和84.15mg/g,腐殖质对Pb2+的饱和吸附量几乎是Cu2+的6.4倍。pH对吸附的影响很大,pH较高时腐殖质具有较大的吸附量。通过IR光谱分析表明,羧基和羟基与重金属离子的络合引起腐殖质对Cu2+和Pb2+的吸附。

Abstract

Modification and preparation of Polyvinyl Acetate(PVAc) as mainly used as adhesive were very important. Urea was added in emulsion-polymerization of Vinvl Acetate (VAc) and N-Hydroxymethyl Acrylamide(NMA), and performances of the emulsion modified before and after were investigated. Results showed that water-resistance, bonding and solid content of PVAc-NMA-Urea were successfully improved. When the mass rate of urea to VAc was 1%~2%, average wet bond strength was 2.04 times than that of PVAc, and average solid content was also 17.85% higher than that of PVAc.

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崔会旺1,2,杜官本1. PVAc-NMA-Urea三元共聚乳液的稳定性和膜性能[J]. 南京林业大学学报(自然科学版). 2007, 31(03): 83-86 https://doi.org/10.3969/j.jssn.1000-2006.2007.03.017
CUI Hui-wang1,2, DU Guan ben1. Study on Stability and Filming of Copolymerization Emulsion PVAc-NMA-Urea[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2007, 31(03): 83-86 https://doi.org/10.3969/j.jssn.1000-2006.2007.03.017
中图分类号: TS727+.5   

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