摘要
<正>通过对1年生印楝实生苗木群体的动态研究,建立了苗木的年生长模型、连日生长量模型和日平均生长量模型。并据此模型将印楝苗木生长节律划分为4个阶段:出苗期(10月中旬至下旬)、生长初期(11月上旬至翌午4月中旬)、速生期(4同下旬至9月下旬)和生长后期(10月上旬至下旬);苗木生物量积累与苗高、地径的函数模型关糸表明,苗术生物量(包括地上部分、地下部分和全株干重)与苗高、地径的相关性极为密切,其中全株干重占全株鲜重的38.8%,地上部分干重占全株鲜重的26.8%,占全株干重的69.1%;同时,以苗高、地径为参考指标,对9个月生的印楝造林苗木进行了数量分级标准划分,并运用该分级标准进行造林试验,结果表明将印楝造林节木从数量指标上划分为I级、Ⅱ级和Ⅲ级是科学合理并切实可行的,其中仅I级与II级可以用作造林合格苗木。
Abstract
Synthesis of the medicinal intermediate (R)-(-)-3-chloro-2-hydroxypropyl tosylate was carried out by the reaction of (R)-(-)-3-chloro-1,2-propanediol and p-toluenesulfonyl chloride in this paper. The influences of the reaction temperature, reaction time, type and dosage of solvent, type and dosage of catalyst, and (R)-(-)-3-chloro-1,2-propanediol/p-toluenesulfonyl chloride ratio on the selectivity of esterification and yield of product were investigated. The suitable synthesis conditions were obtained by optimization with orthogonal experiments: reaction temperature 0°C, reaction time 6h, the molar ratio of p-toluenesulfonyl chloride to (R)-(-)-3-chloro-1,2-propanediol 1.2:1, the molar ratio of catalyst NaOH to (R)-(-)-3-chloro-1,2-propanediol 1.2:1. Ethyl acetate was used as solvent, and the concentration of (R)-(-)-3-chloro-1,2-propanediol was 125g/L. The yield of (R)-(-)-3-chloro-2-hydroxypropyl tosylate was over 85%.
王石发,张明光,李艳苹.
(R)-(-)-3-氯-1,2-丙二醇合成(R)-(-)-3-氯-2-羟丙基对甲苯磺酸酯的研究[J]. 南京林业大学学报(自然科学版). 2007, 31(06): 34-38 https://doi.org/10.3969/j.jssn.1000-2006.2007.06.008
WANG Shi-fa, ZHANG Ming-guang, LI Yan-ping.
Synthesis of Medicinal Intermediate (R)-(-)-3-chloro-2-hydroxypropyl Tosylate from (R)-(-)-3-chloro-1,2-propanediol[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2007, 31(06): 34-38 https://doi.org/10.3969/j.jssn.1000-2006.2007.06.008
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