歧化松香胺席夫碱一铜配合物催化漆酚氧化聚合的研究

雷福厚1,2,蓝虹云2,朱光金2,秦月华2,安鑫南1*

南京林业大学学报(自然科学版) ›› 2005, Vol. 29 ›› Issue (03) : 14-18.

PDF(4263785 KB)
PDF(4263785 KB)
南京林业大学学报(自然科学版) ›› 2005, Vol. 29 ›› Issue (03) : 14-18. DOI: 10.3969/j.jssn.1000-2006.2005.03.004
研究论文

歧化松香胺席夫碱一铜配合物催化漆酚氧化聚合的研究

  • 雷福厚1,2,蓝虹云2,朱光金2,秦月华2,安鑫南1*
作者信息 +

Catalytic Oxypolymerization of Urushiol with Cu2+Schiff Base Complex of Disproportionated Rosin Amine as Catalyst

  • LEI Fu-hou1,2, LAN Hong-yun2, ZHU Guang-jin2, QIN Yue-hua2, AN Xin-nan1*
Author information +
文章历史 +

摘要

<正>以淡竹叶为原料,采用乙醇作为提取溶剂,研究了在微波辐射下提取茶多酚的工艺条件。探讨了茶多酚的提取方法及相应的提取条件;对微波功率、溶剂浓度、料液比、提取时间和提取级数等影响因素进行了研究,按照GB/T8313-2002标准,用UV-9200型分光光度计对茶多酚的吸光度进行了测定,同时对提取得到的茶多酚收率进行了分析。结果表明,微波辅助法从淡竹叶中提取茶多酚的适宜工艺条件为:淡竹叶在60%乙醇溶液中浓度为0.125g/mL,3级提取,提取功率320W,提取时间4min。此条件下茶多酚收率为1.43%。

Abstract

This paper synthesizes the Cu2+schiff base complex of disproportionated rosin amine, and catalyzes urushiol oxypolymerization to polymer. The rosin amine reacts with the salicylaldehyde to product the schiff alkali, then the schiff alkali reacts with cupric acetate to synthesize the schiff alkali-copper complex. The result shows that catalyst concentration, reaction time, urushiol concentration and temperatures affect the polymer yield in oxypolymerization of urushiol system. Rational reaction condition is that ratio of the Cu2+schiff base complex of disproportionated rosin amine is 3%, urushiol concentration is 68.8 g/L, the system of reaction reacts 36 h at 30~C in alcohol dissolvent. The yield of deposition of polymer is 51.3%in rational reaction condition.

引用本文

导出引用
雷福厚1,2,蓝虹云2,朱光金2,秦月华2,安鑫南1*. 歧化松香胺席夫碱一铜配合物催化漆酚氧化聚合的研究[J]. 南京林业大学学报(自然科学版). 2005, 29(03): 14-18 https://doi.org/10.3969/j.jssn.1000-2006.2005.03.004
LEI Fu-hou1,2, LAN Hong-yun2, ZHU Guang-jin2, QIN Yue-hua2, AN Xin-nan1*. Catalytic Oxypolymerization of Urushiol with Cu2+Schiff Base Complex of Disproportionated Rosin Amine as Catalyst[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2005, 29(03): 14-18 https://doi.org/10.3969/j.jssn.1000-2006.2005.03.004
中图分类号: TQ351   

PDF(4263785 KB)

Accesses

Citation

Detail

段落导航
相关文章

/