综合超声法和化学法去除硅酸盐垢的优点,进行了不同条件下的碱溶法和碱性声化学法溶解硅酸盐垢实验,探索低温、常压条件下清除废纸脱墨热分散盘片硅酸盐垢的可行性及较佳技术参数。研究结果表明:无超声时,15 % NaOH溶液90 ℃反应3 h后的溶垢率只有2405 %;加超声后,5 % NaOH溶液90 ℃或10 % NaOH溶液80 ℃反应1 h后的溶垢率高达60 %;而相同条件下,声化学的溶垢率是碱法溶垢率的401~945倍。超声与化学结合的声化学除垢方法,能够快速、安全、清洁、有效地溶解热分散机盘片上的硅酸盐垢,溶垢率最高可达6327 %。
Abstract
The comparative tests of removing silicate scale with alkalinedissolving and alkaline ultrasonicdissolving methods was carried out considering their merits of ultrasonic and chemical methods, and the feasibility and the optimal technical parameters of removing the silicate scale rapidly and safely at low temperature and normal atmosphere were examined at different conditions of alkaline andultrasonicalkaline methods. The results showed that the scaleremoving efficiency was only 24.05 % when using 15 % NaOH solution at 90 ℃ for 3 h. However, the scaleremoving efficiency reached to 60 % in 5 % NaOH solution at 90 ℃ for 1 h or in 10% NaOH solution at 80 ℃ for 1 h when combining with ultrasonic method. It was indicated that the dissolving rate of silicate scale in the ultrasonic solution was 4.01—9.45 times faster than that of in nonultrasonic solution. Therefore, silicate scale on disk disperser could be dissolved quickly, safely, cleanly and effectively by phonochemistry, the highest ratio of dissolving silicate scale was up to 63.27 %.
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基金
收稿日期:2010-11-07修回日期:2011-03-26 基金项目:江苏省属高校自然科学重大基础研究重点项目(08KJA530003);江苏省制浆造纸科学与技术重点实验室开放基金(200924)作者简介:杨红(1984—),硕士生。*张辉(通信作者),教授。Email:hgzh@njfu.edu.cn。