Jiangsu Provincial Key Lab of Pulp and Paper Science and Technology, College of Light Industry Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
Lignin is an abundant natural aromatic renewable resource on earth. A 180years long history has been past from the discovery of lignin to the determination of lignin aromatic compounds, and its basic types of functional groups and chemical structure. However, the speed of lignin research is slowed down due to the complexity and variability of lignin structure. The author describes the formation of lignin and their chemistry research system, reviews the development of lignin study, analyzes the characteristics and difficulties of lignin research, and highlights future research direction and hot topics.
LI Zhongzheng.
Research on renewable biomass resource—lignin[J]. Journal of Nanjing Forestry University (Natural Sciences Edition）. 2012, 36(01): 1-7 https://doi.org/10.3969/j.jssn.1000-2006.2012.01.001
中图分类号：
TQ351
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1]Sarkanan K V, Ludwig C H. Lignin,Occurrence,Formation,Strcture and Reaction[M]. New York:WileyInterscience, 1971. [2]Erich Adler. Lignin chemistry:past, present, future[J]. Wood Science and Technology,1977， 11(1): 169-217. [3]Sjstrm E. Wood Chemistry[M]. New York: Academic Press, 1981. [4]日本纸パルプ技术协会.亚硫酸盐パルプ，溶解パルプ[M].东京：纸パルプ技术协会，1966. [5]中野凖三.木质素的化学-基础与应用[M].李忠正，高洁，译.北京：中国轻工业出版社，1988. [6]Lewin M, Goldstein I S. Wood Structure and Composition[M]. New York:Marrcel Derker, Inc,1991. [7]Lange P. The distribution of lignin in the cell wall of normal and reaction wood from space and few hardwood[J]. Svensk, Paperstidn, 1954, 57:525. [8]Freudenberg K. Zur kenntnis des lignin[J]. Chem Ber, 1936,69:1415. [9]Freudenberg K. Constitution and Biosynthesis of Lignins[M]. Bertin Heidelberg, New York: Springer, 1968. [10]Vanholme R, Morreel K, Ralph J, et al. Lignin engineering [J]. Current Opinion in Plant Biology, 2008, 11:278-285. [11]中野凖三.木材化学[M].李忠正,鲍禾,译.北京:中国林业出版社，1989. [12]ChenLoung Chen. Wood Structure and Composition, Part 5, Lignin: Occurrence in Woody Tissues,Isolation, Reaction,and Structure[M]. New York:Marcel Dekker Inc, 1991. [13]Fingel D, Wegener G. Wood (Chemistry, Ultrastructure, Reaction ) [M]. Berlin, New York: Walter de Grute, 1984. [14]邰瓞生,潘小琪.禾草木质素的化学特性[J].中国造纸，1989,8（1）：10-15. [15]翟华敏，李忠正.麦草纤维细胞和薄壁细胞木质素特性[J].中国造纸，11（1）：18-21. [16]Brauns F E. The sulforiation of lignins[C]//Brauns F. The Chemistry of Lignin. New York: Academic Press, 1952. [17]Grace T M. Pulp and Paper Manufacture. Alkaline Pulping[R]. Toronto:Canadian Pulp & Paper Association, 1989. [18]Gierer J. Kinetic reactions of lignin during alkline pulping[J]. Svensk Papperstidn, 1979, 17:503. [19]Lin Stephen Y. Methods in Lignin Chemistry[M]. Berlin Heidelberg: SpringerVerlag, 1992. [20]Kim H, Ralph J, Akiyama T. Solutionstate 2D NMR of ballmilled plant cell wall gels in DMSOd6 [J]. Bioenerg Res, 2008, 1:56-66. [21]Kersten P, Cullen D. Extracellular oxidative systems of the lignindegrading basidiomycete Phanerochaete chrysosporium[J]. Fungal Genetics and Biology, 2007,44(2): 77-87. [22]蒋杏芬,邰瓞生，王佩卿. 小麦草LCC特性研究[J].中国造纸学报，1989,4（1）：1-6. [23]Yaku F,Yamada Y,Koshijima T. Lignincarbohydrate complex, partⅡ. Enzymatic degradation of acidic polysaccharide in Bjorkman LCC [J].Holzforschung, 1976, 30(5): 148-156. [24]Micic M, Radokik K, Jeremic M, et al. Study of the lignin model compound supramolecular structure by combination of nearfield scanning optical microscopy and atomic force microscopy [J]. Colloids Surfaces B: Biointerfaces, 2004, 34(1): 33 40. [25]Hond NS, Shiraishi N. Wood and Cellulosic Chemistry[M]. 2nd Ed. New York: Marcel Dekker, 2001. [26]Li S, Lundquist K. A new method for the analysis of phenolic groups in lignins by ′HNMR[J]. Nordic Pulp and Paper Research Journal, 1994, 3: 191-195. [27]Chen C L, Robert D. Characterization of Lignin by ′HNMR and 13CNMR Spectroscopy[M]. New York: Methods Enzymol Elsevier, 1988. [28]Rencoret J, Marques G, Guti rrez A, et al. Isolation and structural characterization of the milledwood lignin from Paulownia fortunei wood[J]. Industrial Crops and Products, 2009, 30(1): 137-143. [29]Rezanowich A, Yean W Q, Goring D A I. High resolution electron microscopy of sodium lignin sulfonate[J]. J Appl Polymer Sci, 1964, 8(4): 1801-1812. [30]Gravitis J. 11th ISWPC, Proceeding Ⅲ[R]. Nice, France:ISWPC, 2001. [31]Bjrkman A. Studies on finely divided wood. Part I. Extraction of lignin with neutral solvents[J]. Svensk Papperstidn, 1956, 59(13): 477-485. [32]Lawoko M, Hennksson G, Gellerstedt G. Structural differences between the lignincarbohydrate complexes present in wood and in chemical pulps[J]. Biomacromolecules, 2005, 6: 3467-3473. [33]Nagamatsu Y. 10th ISWPC, Proceeding Ⅲ[R]. Yokohama, Japan:ISWPC, 1999. [34]Stenius P. Forest Products Chemistry[M]. Jyvaskyla, Finland: Gummerus Printing, 2000. [35]李忠正. 工业木质素资源利用的现状与发展[J].中国造纸,2003，22(5)：47-51. [36]刘程.表面活性剂应用大全[M]. 北京：北京工业大学出版社， 1992.
PDF(1556402 KB)
