生物质气化技术的再认识

doi:10.3969/j.issn.1000-2006.2013.01.001

国家林草科技领军期刊
中国精品科技期刊
中国高校百佳科技期刊
江苏省新闻出版政府奖期刊奖
RCCSE林学权威期刊（A+）
CSCD核心期刊
Scopus数据库收录期刊
中文核心期刊
SCD核心期刊

作者加群：102861116

微信公众号：南京林业大学学报

高级检索

南京林业大学学报（自然科学版） ›› 2013, Vol. 37 ›› Issue (01): 1-10.doi: 10.3969/j.issn.1000-2006.2013.01.001

• 特稿 • 下一篇

生物质气化技术的再认识

张齐生，马中青，周建斌

南京林业大学竹材工程研究中心江苏南京 210037

出版日期:2013-02-18 发布日期:2013-02-18
基金资助:

收稿日期：2012-12-05 修回日期：2012-12-20

基金项目：国家重点基础研究发展计划（2010CB732205）；“十二五”国家科技支撑计划（2012BAD30BOO）；“十二五”农村领域国家科技计划（2011BAD15B05-04）；国家林业公益性行业科研专项项目（201004001）

第一作者：张齐生，教授，中国工程院院士。E-mail: zqsnjfu @gmail.com。

History, challenge and solution of biomass gasification: a review

ZHANG Qisheng, MA Zhongqing, ZHOU Jianbin

Bamboo Engineering Research Center, Nanjing Forestry University, Nanjing Jiangsu, 210037

Online:2013-02-18 Published:2013-02-18

摘要/Abstract

摘要： 近现代!生物技术在工业$农业和能源领域得到广泛应用!对世界科技和经济发展起到重大的变革和促进作用% 由于化石燃料资源性枯竭问题和环境污染问题!寻找一种清洁$可再生的替代燃料和燃料生产技术已迫在眉睫，生物质气化技术作为一种清洁的可再生能源利用技术得到了快速发展，然而由于气化设备自身不够成熟以及未对气化副产物"生物质炭和生物质提取液# 加以有效利用等问题!严重阻碍了生物质气化技术的商业化推广和运行% 生物质气化多联产技术是指基于生物质下吸式固定床气化的气$固$液三相产品多联产及其产品分相回收$利用技术% 该技术的提出!以及相关核心设备的开发成功与应用!为生物质气化技术的进一步发展提供了新的思路% 笔者详细介绍了气化技术发展的历史和困境$生物质气化多联产技术的路线和核心设备以及多联产技术产品的开发和应用情况。

Abstract: Recently, as the widely application of biotechnology in the industry, agriculture and energy, it has been playing a great role in technology reform and economy growth. And currently, due to the problems of rapid depletion of fossil fuel and environmental pollution, people are looking for a renewable and green fuel and fuel processing technology that can partially replace the fossil fuel. Biomass gasification technology, regarding as a renewable and sustainable bio-energy conversion technology, has been developing rapidly. However, for the immature gasification system and uneffective recycling utilization of gasification byproducts (bio-char and bio-extract) seriously, it hinders the commercialization and operation of gasification technology. Biomass gasification poly-generation technology is defined as the comprehensive utilization of gas (producer gas), solid (bio-char) and liquid (bio-extract) products from biomass downdraft fixed bed gasification system. The presentation of the poly-generation methodology and the successful application of the associated equipment provide a new guideline for the further development of biomass gasification technology. This paper describes the history, challenge and solution of biomass gasification technology

中图分类号:

. 生物质气化技术的再认识
[J]. 南京林业大学学报（自然科学版）, 2013, 37(01): 1-10.

ZHANG Qisheng, MA Zhongqing, ZHOU Jianbin. History, challenge and solution of biomass gasification: a review[J].Journal of Nanjing Forestry University (Natural Science Edition), 2013, 37(01): 1-10.DOI: 10.3969/j.issn.1000-2006.2013.01.001.

参考文献

[1] 石元春.生物质能源主导论——为编制国家“十二五”规划建言献策[J]. 能源与节能，2011(1)：1-7.

Shi Y C. Discusses of taking bioenergy as the dominant energy—— advice and suggestions for the preparation of the national “Twelfth Five-Year” Plan[J]. Energy and Energy Conservation, 2011(1):1-7.

[2] 石元春. 决胜生物质[M]. 北京：中国农业大学出版社，2011.

[3] Wu C Z, Yin X L, Yuan Z H, et al. The development of bioenergy technology in China[J]. Energy, 2010, 35:4445-4450.

[4] Ma L, Wang T, Liu Q, et al. A review of thermal-chemical conversion of lignocellulosic biomass in China[J]. Biotechnology Advances, 2012, 30:859-873.

[5] 石元春. 中国生物质原料资源[J]. 中国工程科学，2011，13(2)：16-23.

Shi Y C. China’s resources of biomass feedstock [J]. Engineering Science, 2011, 13(2):16-23.

[6] 马隆龙，吴创之，孙立. 生物质气化技术及其应用[M]. 北京：化学工业出版社，2003.

[7] Kumar A, Jones D D, Hanna M A. Thermochemical biomass gasification: A review of the current status of the technology [J]. Energies, 2009(2 ):556-581.

[8] Kirkels A F, Verbong G P J. Biomass gasification: Still promising? A 30-year global overview[J]. Renewable & Sustainable Energy Reviews, 2011, 15:471-481.

[9] Pereira E G, Silva J N, Oliveira J L, et al. Sustainable energy: A review of gasification technologies[J]. Renewable & Sustainable Energy Reviews, 2012, 16:4753-4762.

[10] Panwar N L, Kothari R, Tyagi V V. Thermo chemical conversion of biomass-Eco friendly energy routes [J]. Renewable & Sustainable Energy Reviews, 2012, 16:1801-1816.

[11] Kaupp A, Goss J R. State of The Art Report For Small Scale (to 50 kW) Gas Producer-Engine systems[M]. Final report to USDA, Forest Service, 1981.

[12] Reed T B, Das A. Handbook of biomass downdraft gasifier engine system [M]. USA: The Biomass Energy Foundation Press. 1988.

[13] 张齐生，周建斌，屈永标. 农林生物质的高效、无公害、资源化利用[J]. 林产工业，2009，36(1)：3-8

Zhang Q S, Zhou J B, Qu Y B. High efficiency and pollution free utilization of agriculture and forestry biomass[J]. China Forest Products Industry, 2009, 36(1):3-8

[14] Ma Z, Zhang Y, Zhang Q, et al. Design and experimental investigation of a 190 kWe biomass fixed bed gasification and polygeneration pilot plant using a double air stage downdraft approach[J]. Energy, 2012, 46:140-147.

[15] 秦恒飞，周建斌，张齐生,等. 牛粪固定床气化多联产工艺[J]. 农业工程学报，2011，27(6)：288-293

Qin H F, Zhou J B, Zhang Q S, et al. Poly-generation process for gasification of dairy manure with fixed bed[J].Transcations of the CASE, 2011, 27(6):288-293

[16] Martinez J D, Mahkamov K, Andrade R V, et al. Syngas production in downdraft biomass gasifiers and its application using internal combustion engines[J]. Renewable Energy, 2012, 38:1-9.

[17] Bhattacharya S C, Siddique A H M, Pham H L, et al. A study on wood gasification for low-tar gas production[J]. Energy, 1999, 24: 285-296.

[18] Bhattacharya S C, Hla S S, Pham H L. A study on a multi-stage hybrid gasifier-engine system[J]. Biomass & Bioenergy, 2001, 21:445-460.

[19] Dogru M, Howarth C R, Akay G, et al. Gasification of hazelnut shells in a downdraft gasifier[J]. Energy,2002, 27:415-427.

[20] Leung D Y C, Yin X L, Wu C Z. A review on the development and commercialization of biomass gasification technologies in China[J]. Renewable & Sustainable Energy Reviews, 2004, 8:565-580.

[21] Beebacker A A C M. Biomass gasification in moving beds, a review of european technologies[J]. Renewable energy, 1999,16,1180-1186.

[22] Prabir Basu. 生物质气化和热解：实用设计与理论[M]. 北京：科学出版社，2011.

[23] Lv P, Yuan Z H, Ma L L, et al. Hydrogen-rich gas production from biomass air and oxygen/steam gasification in a downdraft gasifier[J]. Renewable Energy, 2007, 32:2173-2185.

[24] Buragohain B, Mahanta P, Moholkar V S. Biomass gasification for decentralized power generation: The Indian perspective[J]. Renewable & Sustainable Energy Reviews, 2010, 14:73-92.

[25] Pathak B S, Patel S R, Bhave A G, et al. Performance evaluation of an agricultural residue-based modular throat-type down-draft gasifier for thermal application[J]. Biomass & Bioenergy, 2008, 32:72-77.

[26] Sharma A K. Experimental study on 75 kW（th）downdraft (biomass) gasifier system[J]. Renewable Energy, 2009, 34:1726-1733.

[27] Sheth P N, Babu B V. Experimental studies on producer gas generation from wood waste in a downdraft biomass gasifier[J]. Bioresource Technology, 2009, 100:3127-3133.

[28] Sheth P N, Babu B V. Production of hydrogen energy through biomass (waste wood) gasification[J]. International Journal of Hydrogen Energy, 2010;35:10803-10810.

[29] Zainal Z A, Rifau A, Quadir G A, et al. Experimental investigation of a downdraft biomass gasifier[J]. Biomass & Bioenergy, 2002, 23:283-289.

[30] Wei L, Pordesimo L O, Haryanto A, et al. Co-gasification of hardwood chips and crude glycerol in a pilot scale downdraft gasifier[J]. Bioresource Technology, 2011;102:6266-6672.

[31] Plis P, Wilk R K. Theoretical and experimental investigation of biomass gasification process in a fixed bed gasifier[J]. Energy, 2011;36:3838-45.

[32] Midilli A, Dogru M, Howarth C R, et al. Hydrogen production from hazelnut shell by applying air-blown downdraft gasification technique[J]. International Journal of Hydrogen Energy, 2001, 26:29-37.

[33] Olgun H, Ozdogan S, Yinesor G. Results with a bench scale downdraft biomass gasifier for agricultural and forestry residues[J]. Biomass & Bioenergy, 2011, 35:572-580.

[34] Akay G, Jordan C A. Gasification of Fuel Cane Bagasse in a Downdraft Gasifier: Influence of Lignocellulosic Composition and Fuel Particle Size on Syngas Composition and Yield[J]. Energy & Fuels, 2011, 25:2274-2283.

[35] Vera D, Jurado F, Carpio J. Study of a downdraft gasifier and externally fired gas turbine for olive industry wastes[J]. Fuel Processing Technology, 2011;92:1970-1979.

[36] Jain A K, Goss J R. Determination of reactor scaling factors for throatless rice husk gasifier[J]. Biomass and Bioenergy. 2000,18: 249-256

[37] Jarungthammachote S, Dutta A. Thermodynamic equilibrium model and second law analysis of a downdraft waste gasifier[J]. Energy, 2007, 32:1660-9.

[38] Han J, Kim H. The reduction and control technology of tar during biomass gasification/pyrolysis: An overview[J]. Renewable & Sustainable Energy Reviews, 2008, 12:397-416.

[39] Anis S, Zainal ZA. Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review[J]. Renewable & Sustainable Energy Reviews, 2011, 15:2355-2377.

[40] Hasler P, Nussbaumer T. Gas cleaning for IC engine applications from fixed bed biomass gasification[J]. Biomass and Bioenergy, 1999,16:385-395.

[41] Beenackers A A C M. Biomass gasification in moving bed, a review of european technologies[J]. Renewable Energy, 1999, 16:1180-1186.

[42] Chopra S, Jain A K. A review of fixed bed gasification systems for biomass[J]. Agricultural Engineering International: CIGR Journal, NO.5, Volume IX, 1-23, 2007.

[43] Marris E. Putting the carbon back: Black is the new green [J]. Nature, 2006, 442(7103):624-626.

[44]孟军，张伟明，陈温福,等. 农林废弃物炭化还田技术的发展与前景[J]. 沈阳农业大学学报，2011，42(4)：387-392

Meng J, Zhang W M, Chen W F, et al. Development and prospect of carbonization and returning technology of agro-forestry residue[J]. Journal of Shenyang Agriculture University, 2011, 42(4):387-392

[45]陈温福，张伟明，孟军,等. 生物质炭应用技术研究[J]. 中国工程科学，2011，13(2)：83-89

Chen W F, Zhang W M, Meng J, et al. Researches on biochar application technology [J]. Engineering Science, 2011, 13(2):83-89

[46]袁金华，徐仁扣.生物质炭的性质及其对土壤环境功能影响的研究进展[J]. 生态环境学报，2011，20(4)：779-785.

Yuan J H, Xu R K. Progress of the research on the properties of biochars and their influence on soil environmental functions [J]. Ecology and Environmental Sciences, 2011, 20(4):779-785.

[47] 周建斌，段红燕，李思思,等. 杨木炭胶合成型速燃炭的制备与燃烧性能[J]. 农业工程学报，2010，26(6)：257-261

Zhou J B, Duan H Y, Li S S, et al. Preparation and combustion properties of inflammable carbon from polar carbon[J]. Transcations of the CASE, 2010, 26(6):257-261

[48]方放，周建斌，杨继亮. 稻壳炭提取SiO2及制备活性炭联产工艺[J]. 农业工程学报，已录用，1002-6819(2012)-23-0000-08.

Fang F, Zhou J B, Yang J L. Poly-generation research on production of activated carbon and silica extraction from the rice husk charcoal[J]. Transcations of the CASE, 1002-6819(2012)-23-0000-08.

[49]陈健，李庭琛，颜涌捷,等. 生物质裂解残炭制备活性炭[J]. 华东理工大学学报，2005，31(6)：821-824.

Chen J , Li T C, Yan Y J, et al. Preparation of activated carbon from the residual carbon obtained by fast pyrolysis of biomass[J]. Journal of East China University of Science and Technology, 2005, 31(6):821-824.

[50]周建斌，张合玲，张齐生,等. 几种秸秆醋液组分中活性物质的分析[J]. 生物质化学工程，2009，43(2)：34-36.

Zhou J B, Zhang H L, Zhang Q S, et al. Analysis of active substances of several kinds of straw vinegar[J]. Biomass Chemical Engineerinf, 2009, 43(2):34-36.

[51]钱华，钟哲科，王衍彬,等. 竹焦油化学组成的GC/MS法分析[J]. 竹子研究汇刊，2006，25(3)：24-27

Qian H , Zhong Z K, Wang Y B, et al. Analysis of the chemical composition of bamboo tar by GC/MS. [J]. Journal of Bamboo Research, 2006, 25(3):24-27

[52]鲍滨福，马建义，张齐生,等. 竹醋液作为植物生长调节剂的开发研究:(I)田间试验[J].浙江农业学报，2006，18(4)：268-272.

Bao B F, Ma J Y, Zhang Q S, et al. Bamboo vinegar as potential plant growth regulator in stimulative effect: (Ⅱ) the field investigation[J]. Acta Agriculturae Zhejiangensis, 2006, 18(4):268-272.

[53] Mu J, Uehara T, Furuno T. Effect of bamboo vinegar on regulation of germination and radicle growth of Seed Plants [J]. Journal of Wood Science, 2003, 49 (3): 262-270.

[54] Mu J, Uehara T, Furuno T. Effect of bamboo vinegar on regulation of germination and radicle growth of seed plants II: composition of moso bamboo vinegar at different collection temperature and its effects [J]. Journal of Wood Science, 2004, 50 (5):470-476.

[55]魏泉源，刘广青，魏晓明,等. 木醋液作为叶肥施用对芹菜产量及品质的影响[J]. 中国农业大学学报，2009，11(4)：89-92.

Wei Q Y, Liu G Q, Wei X M, et al. Influence of wood vinegar as leaves fertilizer on yield and quality of celery[J]. Journal of China Agriculture University, 2009, 11(4):89-92.

[56]周建斌，叶汉铃，张齐生,等. 麦秸秆醋液的成分分析及抑菌性能研究[J].林产化学与工业，2008，28(4)：55-58.

Zhou J B, Ye H L, Zhang Q S, et al. Study on components and anti-microbial function of wheat-stalk vinegar[J].Chemistry and industry of forest products, 2008, 28(4):55-58.

[57]李维蛟，李强，胡先奇. 木醋液的杀线活性及对根结线虫病的防治效果研究[J].中国农业科学，2009，42(11):4120-4126.

Li W , Li Q , Hu X Q. Nematicidal activity and control efficiency of pyroligeous liquor on meloidogyne spp[J].Scientia Agriculture Sinica, 2009, 42(11):4120-4126.

[58] Li C, Suzuki K. Resources, properties and utilization of tar [J]. Resources, Conservation and Recycling, 2010, 54: 905-915.

[59] Phuphuakrat T, Nipattummakul N, Namioka T, et al. Characterization of tar content in the syngas produced in a downdraft type fixed bed gasification system from dried sewage sludge. [J]. Fuel, 2010, 89:2278-2284.

[60] Bridgwater A V. Review of fast pyrolysis of biomass and product upgrading [J]. Biomass & Bioenergy, 2012, 38:68-94.

[61] Zhang Q, Chang J, Wang T, et al. Review of biomass pyrolysis oil properties and upgrading research[J]. Energy conversion & management, 2007, 48:87-92.

生物质气化技术的再认识

History, challenge and solution of biomass gasification: a review

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

作者

读者

审稿

[1]	马中青，张齐生*，周建斌，章一蒙. 下吸式生物质固定床气化炉研究进展[J]. 南京林业大学学报（自然科学版）, 2013, 37(05): 139-145.
[2]	秦晓,李德生,唐景春,张清敏,高晶. 含盐量对石油污染土壤生物修复的影响[J]. 南京林业大学学报（自然科学版）, 2013, 37(02): 108-112.