麦草碱法黑液热解的产物特性及释放规律

doi:10.3969/j.issn.1000-2006.2013.04.023

国家林草科技领军期刊
中国精品科技期刊
中国高校百佳科技期刊
江苏省新闻出版政府奖期刊奖
RCCSE林学权威期刊（A+）
CSCD核心期刊
Scopus数据库收录期刊
中文核心期刊
SCD核心期刊

作者加群：102861116

微信公众号：南京林业大学学报

高级检索

南京林业大学学报（自然科学版） ›› 2013, Vol. 37 ›› Issue (04): 121-126.doi: 10.3969/j.issn.1000-2006.2013.04.023

麦草碱法黑液热解的产物特性及释放规律

戴涛,武书彬^*,郭大亮,赵玉双,李擘

华南理工大学制浆造纸工程国家重点实验室,广东广州 510640

出版日期:2013-08-18 发布日期:2013-08-18
基金资助:
收稿日期:2012-05-14 修回日期:2013-04-02
基金项目:国家自然科学基金项目(21176095,31270635); 国家重点基础研究发展计划(2013CB228101); 国家高技术研究发展计划(2012AA101806)
第一作者:戴涛,硕士生。*通信作者:武书彬,教授。 E-mail: shubinwu@scut.edu.cn。
引文格式:戴涛,武书彬,郭大亮,等. 麦草碱法黑液热解的产物特性及释放规律[J]. 南京林业大学学报:自然科学版,2013,37(4):121-126.

Study on the product characteristics and release law of pyrolysis of wheat straw black liquor

DAI Tao, WU Shubin^*, GUO Daliang, ZHAO Yushuang, LI Bo

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Online:2013-08-18 Published:2013-08-18

摘要/Abstract

摘要： 对麦草碱法制浆黑液固形物(BLS)400～800 ℃热解产物组成特性进行了研究。采用气相色谱(GC)和气相色谱-质谱(GC-MS)对热解气相产物和液相产物组成进行了全面分析; 利用扫描电镜能谱仪(SEM-EDS)对固相产物的表面形貌及元素分布进行了表征。借助热重红外联用技术(TG-FTIR)探讨了热解过程中主要产物的释放规律。结果表明,BLS热解产物中,气相产物主要成分为H₂、CO、CO₂以及C_xH_y(CH₄、C₂H₂、C₂H₄、C₂H₆)等,液相产物中主要是酚类、酮类、醇类、醚类、酸类、呋喃以及芳香化合物。TG-FTIR结果显示,BLS热解产物释放时间主要集中在1 000～2 000 s(300～600 ℃),此时BLS释放的产物主要为H₂O、CO₂、CH₄、CO,以及烷烃类、芳烃类、酚醇类和酮类化合物。

Abstract: Pyrolysis characteristics of black liquor solid(BLS)was studied on a tubular reactor furnace at 400-800 ℃. The composition of the liquid products and the distribution characteristics of gas products were analyzed by GC-MS and GC. The surface morphology of chars from BLS pyrolysis was characterized by SEM-EDS analysis. The release rule of important volatile matters in BLS pyrolysis process was discussed with the TG-FTIR. The results showed that the main components of the gas products were H₂,CO,CO₂ and C_xH_y(CH₄,C₂H₂,C₂H₄,C₂H₆), and phenols, ketones, alcohols, acids, furans, and aromatic compounds in liquid products. TG-FTIR results revealed that the release time of BLS pyrolysis products mainly concentrated in 1 000-2 000 s(300-600 ℃), at this time, the released products mainly include H₂O, CO₂, CH₄, CO and alkanes, aromatics, phenols, alcohols and ketone compounds.

中图分类号:

X793

戴涛,武书彬,郭大亮,等. 麦草碱法黑液热解的产物特性及释放规律[J]. 南京林业大学学报（自然科学版）, 2013, 37(04): 121-126.

DAI Tao, WU Shubin, GUO Daliang, ZHAO Yushuang, LI Bo. Study on the product characteristics and release law of pyrolysis of wheat straw black liquor[J].Journal of Nanjing Forestry University (Natural Science Edition), 2013, 37(04): 121-126.DOI: 10.3969/j.issn.1000-2006.2013.04.023.

参考文献

[1] Larson E D, Consonni S, Katofsk R E, et al. A cost-benefit assessment of gasification-based biorefining in the kraft pulp and paper industry[R]. New Jersey, USA: The U.S. Department of Energy and the American Forest and Paper Association, 2006.
[2] Dickinson J A, Verrill C L, Kitto J B. Development and evaluation of a low-temperature gasification process for chemical recovery from kraft black liquor[R]. Florida:International Chemical Recovery Conference,1998.
[3] Eriksson H, Harvey S. Black liquor gasification-consequences for both industry and society[J]. Energy,2004,29(4):581-612.
[4] Bhattacharya P K, Shrinath A S, Kunzru D. Pyrolysis of black liquor[J]. Journal of Chemical Technology and Biotechnology, 1985,35A(5):223-233.
[5] Sricharoenchaikul V, Hicks A L, Frederick W J. Carbon and char residue yields from rapid pyrolysis of kraft black liquor[J]. Bioresource Technology, 2001, 77(2):131-138.
[6] Viboon Sricharoenchaikul, Wm James Frederick Jr, Pradeep Agrawal. Carbon distribution in char residue from gasification of kraft black liquor[J]. Biomass and Bioenergy, 2003, 25(2):209-220.
[7] 郭伊丽, 武书彬, 王少光, 等. 黑液热裂解行为的初步研究[J]. 中国造纸, 2006,25(12):65-67. Guo Y L, Wu S B, Wang S G, et al. Preliminary study of the black liquor pyrolysis behavior[J]. China Pulp & Paper, 2006,25(12):65-67.
[8] Guo D L, Wu S B, Lou R,et al. Effect of organic bound Na groups on pyrolysis and CO₂-gasification of alkali lignin[J]. Bioresources, 2011,6(4):4145-4157.
[9] Yang H P, Yan R, Chen H P, et al. Characteristics of hemicellulose, cellulose and lignin pyrolysis[J]. Fuel, 2007,86(12 /13):1781-1788.
[10] 谭洪. 生物质热解机理试验研究[D]. 杭州:浙江大学, 2005. Tan H. Mechanism study of biomass pyrolysis[D]. Hangzhou:Zhejiang University, 2005.
[11] Cetin E, Moghtaderi B, Gupta R, et al. Influence of pyrolysis conditions on the structure and gasification reactivity of biomass chars[J]. Fuel, 2004, 83(16):2139-2150.
[12] Connolly T S. CO₂ pyrolysis and gasification of kraft black liquor char[D]. Maine:The University of Maine, 2006.
[13] Liu Q, Wang S, Zheng Y, et al. Mechanism study of wood lignin pyrolysis by using TG-FTIR analysis[J]. Journal of Analytical and Applied Pyrolysis, 2008, 82(1):170-177.
[14] Jiang X G, Li C Y, Wang T, et al. TG-FTIR study of pyrolysis products evolving from dyestuff production waste[J]. Journal of Analytical and Applied Pyrolysis, 2009, 84(1):103-107.
[15] Greenwood P F, van Heemst J D H, Guthrie E A, et al. Laser micropyrolysis GC-MS of lignin [J]. J Anal Appl Pyrol, 2002, 62(2):365-373.
[16] Ferdous D, Dalai A K, Bei S K, et al. Production of H₂ and medium Btu gas via pyrolysis of lignins in a fixed-bed reactor [J]. Fuel Processing Technology, 2001, 70(1):9-26.

麦草碱法黑液热解的产物特性及释放规律

Study on the product characteristics and release law of pyrolysis of wheat straw black liquor

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 3

编辑推荐

Metrics

本文评价

作者

读者

审稿

[1]	陈晨,王晶晶,毛圣陶,苏文鹏,戴红旗. 文化纸白水中溶解物质和胶体物质的来源分析及表征[J]. 南京林业大学学报（自然科学版）, 2015, 39(03): 106-112.
[2]	王哲,李忠正,谷峰. 麦草亚铵法黑液超滤前后的物化性能[J]. 南京林业大学学报（自然科学版）, 2008, 32(03): 61-63.
[3]	殷承启;洪建国. 上流式厌氧污泥床处理造纸工业废水的研究[J]. 南京林业大学学报（自然科学版）, 2004, 28(05): 41-44.