油茶籽快速热裂解及产物分析

doi:10.3969/j.issn.1000-2006.2014.01.020

国家林草科技领军期刊
中国精品科技期刊
中国高校百佳科技期刊
江苏省新闻出版政府奖期刊奖
RCCSE林学权威期刊（A+）
CSCD核心期刊
Scopus数据库收录期刊
中文核心期刊
SCD核心期刊

作者加群：102861116

微信公众号：南京林业大学学报

高级检索

南京林业大学学报（自然科学版） ›› 2014, Vol. 38 ›› Issue (01): 115-118.doi: 10.3969/j.issn.1000-2006.2014.01.020

油茶籽快速热裂解及产物分析

江俊飞¹,应浩^1,2*,王燕杰¹

1.中国林业科学研究院林产化学工业研究所,生物质化学利用国家实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京 210042;
2.中国林业科学研究院林业新技术研究所,北京 100091

出版日期:2014-01-15 发布日期:2014-01-15
基金资助:
收稿日期:2012-12-03 修回日期:2013-09-18
基金项目:国家自然科学基金项目(30972318); 中央级公益性科研院所基本科研业务费专项资金项目(CAFINT2009K02)
第一作者:江俊飞,硕士生。*通信作者:应浩,研究员。E-mail:hy2478@163.com。
引文格式:江俊飞,应浩,王燕杰. 油茶籽快速热裂解及产物分析[J]. 南京林业大学学报:自然科学版,2014,38(1):115-118.

Rapid pyrolysis and product analysis of Camellia oleifera

JIANG Junfei¹,YING Hao^1,2*,WANG Yanjie¹

1. Institute of Chemical Industry of Forest Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. of Forest Chemical Engineering, SFA; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
2. Institute of New Technology of Forestry, CAF, Beijing 100091, China

Online:2014-01-15 Published:2014-01-15

摘要/Abstract

摘要： 采用居里点热裂解仪-气相色谱-质谱(CP-GC-MS)联用分析技术,分别对油茶籽仁和种壳在358～590 ℃条件下进行快速裂解,并对产物组分进行了分析。结果表明,随着温度的增加,热裂解产物中的组分种类逐渐增加。籽仁热裂解产物主要为脂肪酸,此外还包括糠醛、β-香树脂醇和维生素E等附加值比较高的物质; 种壳的热裂解产物中,脂肪酸的含量占5%左右,主要的产物还包括苯酚类化合物,在产物中还检测到糠醛、香草醛和丁子香酚等附加值比较高的化合物。分析认为,油茶种壳的热裂解产物包含多种工业、医药以及食品行业所需求的原料,同时,产物中的长碳链烯烃类物质可作为生物质能源进行利用。

Abstract: The product components from rapid pyrolysis of Camellia oleifera were analyzed by GC/MS as curie-point temperatures were from 358 ℃ to 590 ℃. Results showed that composition of products tended to be more complex when increased the temperature. The dominated composition in products from rapid pyrolysis of nucleus of C. oleifera was fatty acid and some high value added species such furfural, vitamin E and beta-Amyrin were detected simultaneously. The fatty acid of about 5% from rapid pyrolysis of seed shell of C. oleifera was lower when compared with that in nucleus and the major components were also included the phenols and its derivant. In addition, high value added species such as furfural, vanillin and eugenol were detected in it. The further study indicated that rapid pyrolysis of C. oleifera could provid many raw materials for chemical industry, pharmaceuticals industry and food industry.

中图分类号:

TQ203

江俊飞,应浩,王燕杰. 油茶籽快速热裂解及产物分析[J]. 南京林业大学学报（自然科学版）, 2014, 38(01): 115-118.

JIANG Junfei,YING Hao,WANG Yanjie. Rapid pyrolysis and product analysis of Camellia oleifera[J].Journal of Nanjing Forestry University (Natural Science Edition), 2014, 38(01): 115-118.DOI: 10.3969/j.issn.1000-2006.2014.01.020.

参考文献

[1] 吴小娟,李红冰,逄越,等.山茶和油茶种子中脂肪酸的分析[J].大连大学学报,2006,27(4):56-58.Wu X J, Li H B, Pang Y, et al. Analyse of fatty acids composition in the seeds of C. japonica L.and C. oleifera Abel[J]. Journal of Dalian University, 2006, 27(4):56-58.
[2] 肖志红,陈永忠.油茶加工利用研究综述[J].林业科技开发,2005,19(2):10-13.Xiao Z H, Chen Y Z. Research on processing and utilization of Camellia oleifera [J]China Forestry Science and Technology, 2005, 19(2):10-13.
[3] 王开良,曹福亮,姚小华,等.浙江红花油茶茶油中脂肪酸主要成分分析[J].南京林业大学学报:自然科学版,2011,35(2):131-134.Wang K L, Cao F L, Yao X H, et al. Chemical composition of fatty acid from Camellia chekiangoleosa Hu[J]. Journal of Nanjing Forestry University:Natural Sciences Edition, 2011, 35(2):131-134.
[4] 刘芳,黄科瑞,黎远成.微波辅助提取油茶籽油的工艺优化[J].中国农学通报,2012,28(3):290-294.Liu F, Huang K R, Li Y C. Process optimization for microwave-assisted extraction of Camellia oleifera[J]. Chinese Agricultural Science Bulletin, 2012, 28(3):290-294.
[5] 周倩,范成钢,聂芸,等.超声波辅助提取油茶籽油工艺条件研究[J].中国粮油报,2011,26(5):61-65. Zhou Q, Fan C G, Nie Y, et al. Study on process conditions for ultrasound-assisted extraction of Camellia seed oil[J]. Journal of the Chinese Cereals and Oils Association, 2011, 26(5):61-65.
[6] 卢泽湘,范立维,郑德勇,等.超临界C0₂萃取油茶籽油的工艺及其脂肪酸成分分析[J].福建林学院学报,2010,30(4):344-348.Lu Z X, Fan L W, Zheng D Y, et al. Technology for supercritical CO₂ extraction of Camellia oleifera seed oil and analysis of the fatty acids[J] Journal of Fujian College of Forestry,2010, 30(4):344-348.
[7] 郭玉宝,屠康磁,薛正莲,等.盐效应辅助水相萃取油茶籽油的工艺[J].农业工程学报,2010,26(9):362-367.Guo Y B, Tu K C, Xue Z L, et al. Technology for aqueous extraction of Camellia seed oil by salt effect[J]. Transactions of the Chinese Society of Agricultural Engineering, 2010, 26(9):362-367.
[8] 李文林,黄凤洪,王利宾.油茶籽加工和综合利用研究进展[J].中国油脂,2011,36(11):55-57.Li W L, Huang F H, Wang L B. Review on processing and comprehensive utilization of oil tea Camellia seed[J]. China Oils and Fats, 2011, 36(11):55-57.
[9] 张可,钱和,张添.油茶籽的综合开发利用[J].食品科技,2003(4):85-86.Zhang K, Qian H, Zhang T. The multipurpose utilization of Camellia oleifera seed[J]. Food Science and Technology, 2003(4):85-86.
[10] Sun K, Jiang J C, Cui D D. Preparation of activated carbon with highly developed mesoporous structure from Camellia oleifera shell through water vapor gasification and phosphoric acid modification[J]. Biomass and Bioenergy, 2011, 35(8):3643-3647.
[11] 沈建福,康海权,陈亚琪,等.油茶果壳多糖的提取及抗氧化作用研究[J].中国粮油学报,2010,25(8):51-54.Shen J F, Kang H Q, Chen Y Q, et al. Polysaccharides from fruit shell of Camellia oleifera Abel:extraction and antioxidation activity[J]. Journal of the Chinese Cereals and Oils Association, 2010, 25(8):51-54.
[12] 杨小敏,刘建平,李倩倩,等.用改良硫酸法从油茶壳中提取糠醛的响应面法优化[J].农业机械学报,2011,42(5):151-155.Yang X M, Liu J P, Li Q Q, et al. Optimization of furfural extraction from Camellia oleifera Abel nutshell by response surface methodology[J]. Transactions of the Chinese Society for Agricultural Machinery, 2011, 42(5):151-155.
[13] Gu X L, Ma X, Li L X, et al. Pyrolysis of poplar wood sawdust by TG-FTIR and Py-GC/MS[J]. Journal of Analytical and Applied Pyrolysis, 2013,102:16-23.
[14] 彭万喜,张宁南,张党权,等.檀香叶抽提物成分的Py-GC /MS分析[J]. 华南理工大学学报:自然科学版,2008,36(11):38-44.Peng W X, Zhang N N, Zhang D Q, et al. Determination of chemical components of extractives from Santalum album L. leaves by means of Py-GC/MS[J]. Journal of South China University of Technology:Natural Science Edition, 2008, 36(11):38-44.
[15] 彭万喜,武书彬,吴义强,等.尾巨桉树皮高品位资源化利用的Py-GC-MS分析[J].林产化学与工业,2008,28(4):87-92.Peng W X, Wu S B, Wu Y Q, et al. Analysis on high-grade resource utilization of Eucalyptus urophydis bark by Py-GC-MS[J].Chemistry and Industry of Forest Products,2008,28(4):87-92.
[16] 张党权,彭万喜,刘其梅,等.油茶壳高品位资源化利用的Py-GC/MS分析[J].中国粮油学报,2008,23(6):161-165.Zhang D Q, Peng W X, Liu Q M, et al. Py-GC/MS analysis to estimate high-grade resource recovery of Camellia oleifera shell[J]. Journal of the Chinese Cereals and Oils Association, 2008, 23(6):161-165.

油茶籽快速热裂解及产物分析

Rapid pyrolysis and product analysis of Camellia oleifera

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价

作者

读者

审稿