天然纤维/聚合物复合材料的研究进展

黄润州,冒海燕,梅长彤,徐信武,WUQinglin

南京林业大学学报(自然科学版) ›› 2016, Vol. 40 ›› Issue (03) : 163-169.

PDF(1993044 KB)
PDF(1993044 KB)
南京林业大学学报(自然科学版) ›› 2016, Vol. 40 ›› Issue (03) : 163-169. DOI: 10.3969/j.issn.1000-2006.2016.03.027
综合述评

天然纤维/聚合物复合材料的研究进展

  • 黄润州1,2,冒海燕1,梅长彤1,徐信武1,WU Qinglin2
作者信息 +

Research status and prospect of nature fiber reinforced polymer composites

  • HUANG Runzhou1,2, MAO Haiyan1,MEI Changtong1, XU Xinwu1, WU Qinglin2
Author information +
文章历史 +

摘要

从传统均相结构、共挤出型芯-表结构的天然纤维/聚合物复合材料、纳米纤维素及微(纳)米纤维/聚合物复合材料3个方面综述了国内外利用天然纤维增强聚合物复合材料的研究现状。芯-表结构的天然纤维/聚合物复合材料(NFPC)作为新型的绿色环保型材料已成为研究热点。使用芯-表结构可以显著改善复合材料的综合性能,大大提高复合材料的使用率,并使其在原料使用和材料性能与功能上更符合循环经济和绿色环保的原则。芯-表结构NFPC的芯层与表层间的界面性能是影响芯-表结构NFPC整体性能的主要因素。在此基础上,笔者从农作物纤维/聚合物复合材料的高值化应用的角度,分析了天然纤维/聚合物复合材料研究方向和应用方面存在的主要问题及解决思路。

Abstract

As a new-generation green composite, nature fibers/ polymer composites(NFPC), mading of thermoplastics filled with nature agriculture fibers and other additives, has been recently developed and used to enhance performance characteristics of composites. In this paper, typical NFPC,core-shell structure NFPC(co-extrusion)and cellulose nanofibers(CNFs)and its filled composites have been systematically reviewed. The shell layer, mading of thermoplastics unfilled or filled with minerals or nature fibers and other additives, plays a critical role in enhancing overall composite properties. A fundamental understanding of the interactions between shell and core layers with different structural and material combinations is, however, needed to achieve desired product performance. The results of this paper can help to provide a fundamental base for developing new functional applications of NFPC.

引用本文

导出引用
黄润州,冒海燕,梅长彤,徐信武,WUQinglin. 天然纤维/聚合物复合材料的研究进展[J]. 南京林业大学学报(自然科学版). 2016, 40(03): 163-169 https://doi.org/10.3969/j.issn.1000-2006.2016.03.027
HUANG Runzhou, MAO Haiyan,MEI Changtong, XU Xinwu, WU Qinglin. Research status and prospect of nature fiber reinforced polymer composites[J]. Journal of Nanjing Forestry University (Natural Sciences Edition). 2016, 40(03): 163-169 https://doi.org/10.3969/j.issn.1000-2006.2016.03.027
中图分类号: TB332    S781   

参考文献

[1] James W L. Research needs in wood physics:a broad overview [J]. Wood and Fiber Science, 1988, 20(2): 277-294.
[2] Son J, Gardner D J, O'Neill S, et al. Understanding the viscoelastic properties of extruded polypropylene wood plastic composites [J]. Journal of Applied Polymer Science, 2003,89(6):1638-1644.
[3] Klyosov A A. Wood plastic composites[M]. Hoboken: John Wiley & Sons Inc., 2007: 698.
[4] Nielsen L E, Landel R F. Mechanical properties of polymers and composites [M]. 2nd edition. New York: Marcel Dekker, 1993.
[5] Liu H Z, Yao F, Xu Y J, et al. A novel wood flour-filled composite based on microfibrillar high-density polyethylene(HDPE)/nylon-6 blends [J]. Bioresource Technology, 2010, 101(9):3295-3297.
[6] Yao F, Wu Q L, Lei Y, et al. Rice straw fiber-reinforced high-density polyethylene composite: effect of fiber type and loading [J]. Industrial Crops and Products, 2008, 28(1): 63-72.
[7] Pandey J K, Ahn S-H, Lee C S, et al. Recent advances in the application of natural fiber based composites [J]. Macromolecular Materials and Engineering, 2010, 295(11): 975-989.
[8] 黄润州. 芯-表结构木塑复合材料机械性能与热膨胀性能的研究[D]. 南京:南京林业大学, 2012. Huang R Z.Mechanical and thermal expansion properties of the core-shell structure wood plastic composites[D]. Nanjing: Nanjing Forestry University, 2012.
[9] Bengtsson M, Oksman K. Silane crosslinked wood plastic composites: processing and properties [J]. Compos Sci Technol, 2006, 66(13): 2177-2186.
[10] Lei Y, Wu Q L, Clemons C M, et al. Influence of nanoclay on properties of HDPE/wood composites [J]. Journal of Applied Polymer Science, 2007, 106(6): 3958-3966.
[11] Jiang L, Wolcott M P, Zhang J W, et al. Flexural properties of surface reinforced wood/plastic deck board [J]. Polymer Engineering and Science, 2007, 47(3): 281-288.
[12] 李兰杰,朱胜杰,刘赞,等. 干燥处理对PF/松木粉复合材料性能的影响[J].合成树脂及塑料,2005,22(3):22-25. Li L J, Zhu S J, Liu Z, et al.Effect of drying treatment on properties of wood flour/PE composite[J]. China Synthetic Resin and Plastics, 2005,22(3): 22-25.
[13] 胡圣飞,刘维华,郦华兴,等. PP/纳米CaCO3/木粉复合材料研究[J]. 湖北工学院学报,2004, 19(6):1-3. Hu S F, Liu W H, Li H X, et al. Study on PP/nano-CaCO3/wood flour composites[J]. Journal of Hubei Polytechnic University, 2004, 19(6):1-3.
[14] 朱晓群,周亨近,魏浩,等.木粉/HDPE复合材料的力学性能与流动性能[J]. 北京化工大学学报,2001,28(1): 56-58. Zhu X Q, Zhou H J, Wei H, et al. Mechanical and fluid properties of wood flour/high density polyethylene composite[J]. Journal of Beijing University of Chemical Technology, 2001,28(1): 56-58.
[15] 李思良,曾湘云,刘希凡. 木粉填充PP的力学性能[J]. 中国塑料,1998,12(4):33-36. Li S L, Zeng X Y, Liu X F. The mechanical properties of PP filled with wood meals [J]. China Plastics, 1998,12(4):33-36.
[16] 杨鸣波,李忠明,冯建民,等.秸秆/聚氯乙烯复合材料的初步研究[J]. 材料科学与工程, 2000, 18(4): 27-29. Yang M B, Li Z M, Feng J M, et al.Studies on wheat straw/poly(vinyl chloride)composite[J]. Materials Science and Engineering, 2000, 18(4): 27-29.
[17] 董吉,李斌. 膨胀型阻燃剂对聚丙烯-木粉复合材料阻燃及性能的影响[J]. 化学与黏合, 2007, 29(4): 269-271. Dong J, Li B.Study on the flame retardation and properties of PP-wood composite material by intumescent flame retardant[J]. Chemistry and Adhesion, 2007, 29(4): 269-271.
[18] AbuBakar M B, Mohd Ishak Z A, Mat Taib R, et al. Flammability and mechanical properties of wood flour-filled polypropylene composites[J]. Journal of Applied Polymer Science, 2010, 116(5): 2714-2722.
[19] Huang R Z, Zhou C J, Zhang Y, et al. Co-extrusion technology for functioned nature fiber reinforced polymer composites[J]. Advanced Materials Research, 2013, 773: 497-501.
[20] Yao F, Wu Q L. Coextruded polyethylene and wood-flour composite: effect of shell thickness, wood loading, and core quality [J]. Journal of Applied Polymer Science, 2010, 118(6): 3594-3601.
[21] Kim B J, Yao F, Han G P, et al. Mechanical and physical properties of core-shell structured wood plastic composites: effect of shells with hybrid mineral and wood fillers [J]. Composites Part B: Engineering, 2013,45(1): 1040-1048.
[22] Huang R Z, Kim B J, Lee S, et al. Co-extruded wood plastic composites with talc-filled shells: morphology, mechanical and thermal expansion performance [J]. Bio Resources, 2013, 8(2): 2283-2299.
[23] Huang R Z, Xiong W, Xu X W, et al. Thermal expansion behavior of co-extruded wood plastic composites with glass-fiber reinforced shells [J]. Bioresources, 2012, 7(4): 5514-5526.
[24] Jin S, Matuana L M. Wood/plastic composites co-extruded with multi-walled carbon nanotube-filled rigid poly(vinyl chloride)cap layer [J].Polym Inter, 2010, 59(5): 648-657.
[25] Doshi S R, Charrier J M, Dealy J M. A coextrusion process for the manufacture of short-fiber-reinforced thermoplastic pipe [J]. Polymer Engineering and Science, 1988, 28(15): 964-973.
[26] El-Salmawy A, Kimura Y. Structure and properties of bicomponent core-sheath fibers from poly(ethylene terephthalate)and biodegradable aliphatic polyesters [J]. Textile Research Journal, 2001,71(2): 145-152.
[27] Hsueh C H, Ferber M K. Apparent coefficient of thermal expansion and residual stresses in multilayer capacitors [J]. Composites Part A: Applied Science and Manufacturing, 2002, 33(8): 1115-1121.
[28] Halpin J C, Pagano N J. The laminate approximation for randomly oriented fibrous composites [J]. J Compos Mater, 1969, 3(4): 720-724.
[29] Soma A, Bressan F, De Bona F. Design of composite laminates with low thermal expansion [J]. Journal of Materials, Design & Applications, 2004, 218: 201-209.
[30] Yu Z, Zhou A X. An integrated thermomechanical method for modeling fiber reinforced polymer composite structures in fire [C]//Structures congress 2010: 19th analysis and computation specialty conference. Orlando, Florida: American society of civil engineers, 2010.
[31] 宋孝周,吴清林,傅峰,等. 农作物与其剩余物制备纳米纤维素研究进展[J]. 农业机械学报,2011,42(11): 106-112. Song X Z, Wu Q L, Fu F, et al.Research progress of nanocrystalline cellulose prepared from crops and agricultural residues [J]. Transactions of the Chinese Society for Agricultural Machinery, 2011, 42(11): 106-112.
[32] Moon C K, McDonough W G. Multiple fiber technique for the single fiber fragmentation test[J]. Journal of Applied Polymer Science, 1998, 67(10): 1701-1709.
[33] Dufresne A. Comparing the mechanical properties of high performances polymer nanocomposites from biological sources [J]. J Nanosci Nanotechnol, 2006, 6(2): 322-330.
[34] Liu D G, Chen X Y, Yue Y Y, et al. Structure and rheology of nanocrystalline cellulose[J]. Carbohydrate Polymers, 2011, 84(1): 316-322.
[35] Liu H Y, Liu D G, Yao F, et al. Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites [J]. Bioresource Technology, 2010, 101(14): 5685-5692.
[36] Zhou C J, Wu Q L, Yue Y Y, et al. Application of rod-shaped cellulose nanocrystals in polyacrylamide hydrogels [J]. Journal of Colloid and Interface Science, 2010, 353(1): 116-123.
[37] Zhou C J, Chu R, Wu R, et al. Electrospun polyethylene oxide/cellulose nanocrystal composite nanofibrous mats with homogeneous and heterogeneous microstructures [J]. Biomacro Molecules, 2011, 12(12): 2617-2625.
[38] Lu J Z, Wu Q L, Negulescu I I. Wood-fiber/high-density-polyethylene composites: coupling agent performance [J]. Journal of Applied Polymer Science, 2005, 96(1): 93-102.
[39] Lu J Z,Negulescu I I, Wu Q L. Maleated wood-fiber/high-density-polyethylene composites: coupling mechanisms and interfacial characterization [J]. Composite Interfaces, 2005, 12(1/2): 125-140.
[40] Lu J Z, Wu Q L. Surface and interfacial characterization of wood-pvc composite: imaging morphology and wetting behavior [J]. Wood and Fiber Science, 2005, 37(1): 95-111.

基金

收稿日期:2015-10-22 修回日期:2016-01-06
基金项目:国家自然科学基金项目(青年基金)(31300482,31500483); 江苏省自然科学基金项目(BK20130966):国家林业局“948”项目(2014-4-49); 江苏高校优势学科建设工程项目(PAPD); 南京林业大学高学历人才基金项目
第一作者:黄润州(runzhouhuang@gmail.com),副教授,博士。
引文格式:黄润州,冒海燕,梅长彤,等. 天然纤维/聚合物复合材料的研究进展[J]. 南京林业大学学报(自然科学版),2016,40(3):163-169.

PDF(1993044 KB)

Accesses

Citation

Detail

段落导航
相关文章

/