氨气冷等离子体预处理聚磷酸铵对稻秸/HDPE复合材料性能的影响

doi:10.3969/j.issn.1000-2006.2016.05.020

国家林草科技领军期刊
中国精品科技期刊
中国高校百佳科技期刊
江苏省新闻出版政府奖期刊奖
RCCSE林学权威期刊（A+）
CSCD核心期刊
Scopus数据库收录期刊
中文核心期刊
SCD核心期刊

作者加群：102861116

微信公众号：南京林业大学学报

高级检索

南京林业大学学报（自然科学版） ›› 2016, Vol. 59 ›› Issue (05): 126-130.doi: 10.3969/j.issn.1000-2006.2016.05.020

氨气冷等离子体预处理聚磷酸铵对稻秸/HDPE复合材料性能的影响

史书凯,蔡欣,周晓燕,潘明珠^*

南京林业大学材料科学与工程学院,江苏南京 210037

出版日期:2016-10-18 发布日期:2016-10-18
基金资助:
收稿日期:2015-08-29 修回日期:2016-01-19
基金项目:国家自然科学基金项目(31300476)
第一作者:史书凯(shishukai@hotmail.com)。*通信作者:潘明珠(mzpan@njfu.edu.cn),副教授,博士。
引文格式:史书凯,蔡欣,周晓燕,等. 氨气冷等离子体预处理聚磷酸铵对稻秸/HDPE复合材料性能的影响[J]. 南京林业大学学报(自然科学版),2016,40(5):126-130.

Effects of ammonia cold plasma pretreatment of ammonium polyphosphate on the properties of rice straw/high density polyethylene composites

SHI Shukai, CAI Xin, ZHOU Xiaoyan, PAN Mingzhu^*

College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China

Online:2016-10-18 Published:2016-10-18

摘要/Abstract

摘要： 为提升聚磷酸铵(ammonium polyphosphate, APP)在稻秸/HDPE(高密度聚乙烯)复合材料中的相容性,采用氨气冷等离子体对APP进行预处理,研究处理功率(100、200、300 W)和处理时间(1、2、3 min)对稻秸/HDPE复合材料阻燃性能和力学性能的影响。极限氧指数(limited oxygen index, LOI)测试结果表明,APP经过氨气冷等离子体预处理后,稻秸/HDPE复合材料的LOI均高于未处理试样; 当处理功率100 W、处理时间3 min时,LOI达到最大,为30.5%,较未处理时增加了10.9%。力学性能测试与双因素方差分析表明,氨气冷等离子体预处理APP对稻秸/HDPE复合材料的拉伸性能和冲击性能影响不显著,处理功率对稻秸/HDPE复合材料的弯曲强度影响显著。

Abstract: Pretreated by ammonia cold plasma, rice straw/high density polyethylene composites(RPC)with ammonium polyphosphate(APP)were prepared. The treatment power(100, 200 and 300 W)and time(1, 2 and 3 min)were carried out to investigate the effects on flame retard and mechanical properties of RPC. Results of limited oxygen index(LOI)showed that, RPC with APP pretreated by ammonia cold plasma exhibited higher LOI compared with the control sample. At a treatment power of 100 W for 3 min, the LOI of RPC with APP pretreated by ammonia cold plasma was 30.5%, increased by 10.9%. The results of the mechanical properties of RPC and two-way ANOVA analysis indicated that RPC with APP pretreated by ammonia cold plasma exerted no significant effect on the tensile properties and impact strength. The treatment power of ammonia cold plasma exerted a significant effect on the flexural strength of RPC.

中图分类号:

TB332

史书凯,蔡欣,周晓燕,等. 氨气冷等离子体预处理聚磷酸铵对稻秸/HDPE复合材料性能的影响[J]. 南京林业大学学报（自然科学版）, 2016, 59(05): 126-130.

SHI Shukai, CAI Xin, ZHOU Xiaoyan, PAN Mingzhu. Effects of ammonia cold plasma pretreatment of ammonium polyphosphate on the properties of rice straw/high density polyethylene composites[J].Journal of Nanjing Forestry University (Natural Science Edition), 2016, 59(05): 126-130.DOI: 10.3969/j.issn.1000-2006.2016.05.020.

参考文献

[1] Garcil M, Hidalgo J, Garmendia I, et al.Wood-plastics composites with better fire retardancy and durability performance[J]. Composites Part A:Applied Science and Manufacturing, 2009, 40: 1772-1776.
[2] 方露, 李大纲,施迎春,等. 阻燃型木塑复合材料研究进展[J]. 中国塑料, 2011, 2(3): 13-17. Fang L, Li D G, Shi Y C, et al.Research progress in flame retardant plastics/wood composites[J]. China Plastics, 2011, 2(3): 13-17.
[3] 潘明珠, 梅长彤. 纳米SiO₂-APP 对木塑复合材料界面特性及力学性能的影响[J]. 北京林业大学学报, 2013, 35(5): 117-122. Pan M Z, Mei C T. Effects of nano SiO₂-ammonium polyphosphate on the interfacial and mechanical properties of wood fiber-polyethylene composites[J]. Journal of Beijing Forestry University, 2013, 35(5): 117-122.
[4] Pan M Z, Mei C T, Du J, et al. Synergistic effect of nano silicon dioxide and ammonium polyphosphate on flame retardancy of wood fiber-polyethylene composites[J]. Composites Part A:Applied Science and Manufacturing, 2014, 66: 128-134.
[5] 徐信武, 周定国. 等离子体改性稻秸的XPS分析[J]. 南京林业大学学报(自然科学版), 2009, 33(5): 69-72.Doi:10.3969/j.issn.1000-2006.2009.05.015. Xu X W, Zhou D G. XPS analysis of rice straw modified with plasma treatment [J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2009, 33(5): 69-72.
[6] 王洪艳, 杜官本. 冷等离子体技术在木竹材表面改性中的应用及研究进展[J]. 化学与黏合, 2013, 35(1): 57-60. Wang H Y, Du G B. The study progress and application of cold plasma in surface modification of wood and bamboo[J]. Chemistry and Adhesion, 2013, 35(1): 57-60.
[7] 林捷. 常压介质阻挡辉光放电及其对有机材料的表面改性作用机理[D]. 上海: 东华大学, 2010. Lin J. Chracteristic of dielectric barrier discharge in atmospheric pressure and its impact on polymer surface modification[D]. Shanghai: Donghua University, 2010.
[8] 赵明. 等离子体处理稠油的机理与研究[D]. 北京: 中国石油大学, 2011. Zhao M. Mechanism and study of updating heavy oil using plasma[D]. Beijing: China University of Petroleum,2011.
[9] Rochette A, Bousmina M, Lavoie A, et al. Effect of surface treatment on mechanical properties of polyethylene composite[J]. Journal of Composite Materials, 2002, 36(8): 925-940.
[10] 潘明珠, 周定国. 不同预处理方法对稻秸纤维表面性质的影响[J]. 纤维素科学与技术, 2007, 15(3): 9-13.Doi:10.3969/j.issn.1004-8405.2007.03.003. Pan M Z, Zhou D G. Effects of different pretreatment on surface characteristic of rice straw fiber[J]. Journal of Cellulose Science and Technology, 2007, 15(3): 9-13.
[11] 章蓉, 周晓燕,汤丽娟,等. 常压冷等离子体处理改善杨木单板胶合特性的研究[J]. 南京林业大学学报(自然科学版), 2013, 37(5): 169-171.Doi:10.3969/j.issn.1000-2006.2013.05.033. Zhang R, Zhou X Y, Tang L J, et al. Improvement bondability of poplar veneers by atmospheric pressure plasma discharge treatment[J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2013, 37(5): 169-171.
[12] 韩文佳. 高密度植物纤维功能材料制备、性能和机理的研究[D]. 广州: 华南理工大学, 2011. Han W J. Research on the preparation,properties and mechanism of high density functional plant fiber materials[D]. Guangzhou: South China University of Technology, 2011.
[13] 梁恩泉. 不同阻燃剂对麦秸纤维/回收聚丙烯复合材料性能的影响[D]. 南京: 南京航空航天大学, 2010. Liang E Q. The influence of different flame retardancy on the properties of wheat straw fiber/recycled polypropylene composite[D]. Nanjing: Nanjing University of Aeronautics and Astronautics, 2010.
[14] 马玉峰. 轻质阻燃酚醛泡沫材料的制备与构效关系研究[D]. 北京: 中国林业科学研究院, 2013. Ma Y F. Preparation and structure-property relationship of light and flame-retardant phenolic foams[D]. Beijing: Chinese Academy of Forestry, 2013.
[15] 王丽. 等离子体催化氨分解制氢的协同效应研究[D]. 大连: 大连理工大学, 2013. Wang L. Synergetic effect between plasma and catalyst in ammonia decomposition for hydrogen production[D]. Dalian: Dalin University of Technology, 2013.
[16] Li S, Han K Q, Rong H P, et al. Surface modification of aramid fibers via ammonia-plasma treatment[J]. Journal of Applied Polymer Science, 2014, 131(10): 40250-40255.
[17] Andreozzi L, Castelvetro V, Ciardelli G, et al. Free radical generation upon plasma treatment of cotton fibers and their initiation efficiency in surface-graft polymerization[J]. Journal of Colloid and Interface Science, 2005, 289(2): 455-465.
[18] 孙洁. 常压等离子体处理高分子材料诱导自由基及其引发表面改性反应的研究[D]. 上海: 东华大学, 2011. Sun J. The mechanism of free radical reactions induced by atmospheric pressure plasma treatment on polymer surfaces[D]. Shanghai: Donghua University, 2011.
[19] 熊艳丽, 王汝敏, 王云芳,等. 等离子体表面改性在高聚物中的应用进展[J].塑料, 2005, 34(3): 19-23.Doi:10.3969/j.issn.1001-9456.2005.03.004. Xiong Y L, Wang R M, Wang Y F, et al. Application progresses of surface modification on polymer by plasma technology[J]. Plastic, 2005, 34(3): 19-23.

氨气冷等离子体预处理聚磷酸铵对稻秸/HDPE复合材料性能的影响

Effects of ammonia cold plasma pretreatment of ammonium polyphosphate on the properties of rice straw/high density polyethylene composites

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 6

编辑推荐

Metrics

本文评价

作者

读者

审稿

[1]	黄润州,梅长彤,徐信武,冒海燕,WUQinglin,戴翔. 皮层对皮-芯结构木塑复合材料性能的影响[J]. 南京林业大学学报（自然科学版）, 2017, 60(05): 135-140.
[2]	刘雪娇,景宜. 羧甲基壳聚糖和季铵盐壳聚糖的制备工艺[J]. 南京林业大学学报（自然科学版）, 2017, 60(03): 151-156.
[3]	韩士群,杨莹,周庆,杨启辉,孟煜. 蒸汽爆破对芦苇纤维及其木塑复合材料性能的影响[J]. 南京林业大学学报（自然科学版）, 2017, 60(01): 136-142.
[4]	黄润州,冒海燕,梅长彤,徐信武,WUQinglin. 天然纤维/聚合物复合材料的研究进展[J]. 南京林业大学学报（自然科学版）, 2016, 59(03): 163-169.
[5]	杜凤,王伟宏. 碳纤维增强木粉/聚乙烯复合材料的制备及其力学性能[J]. 南京林业大学学报（自然科学版）, 2015, 58(02): 132-136.
[6]	秦特夫，吴玉章，黄洛华. 木塑复合材料燃烧性能的研究[J]. 南京林业大学学报（自然科学版）, 2011, 54(01): 71-74.