聚苯乙烯改性纤维素纳米晶体对聚甲基丙烯酸甲酯热稳定性的增强作用

doi:10.3969/j.issn.1000-2006.2016.05.022

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南京林业大学学报（自然科学版） ›› 2016, Vol. 59 ›› Issue (05): 138-142.doi: 10.3969/j.issn.1000-2006.2016.05.022

聚苯乙烯改性纤维素纳米晶体对聚甲基丙烯酸甲酯热稳定性的增强作用

尹园园,田秀枝,朱春波,蒋学^*,王鸿博,高卫东

江南大学纺织服装学院,生态纺织教育部重点实验室,江苏无锡 214122

出版日期:2016-10-18 发布日期:2016-10-18
基金资助:
收稿日期:2015-06-29 修回日期:2015-11-10
基金项目:国家自然科学基金项目(31270632,31570578); 江苏高校优势学科建设工程资助项目(PAPD)
第一作者:尹园园(yy3-yin@hotmail.com)。*通信作者:蒋学(jiangx@jiangnan.edu.cn),副教授。
引文格式:尹园园,田秀枝,朱春波,等. 聚苯乙烯改性纤维素纳米晶体对聚甲基丙烯酸甲酯热稳定性的增强作用[J]. 南京林业大学学报(自然科学版),2016,40(5):138-142.

Reinforcement on the thermal stability of poly(methyl methacrylate)of cellulose nanocrystals modified with polystyrene

YIN Yuanyuan, TIAN Xiuzhi, ZHU Chunbo, JIANG Xue^*, WANG Hongbo, GAO Weidong

Key Laboratory of Eco-textiles of Ministry of Education, College of Textiles and Clothing, Jiangnan University, Wuxi 214122, China

Online:2016-10-18 Published:2016-10-18

摘要/Abstract

摘要： 采用原子转移自由基聚合(SI-ATRP)在纤维素纳米晶体(CNC)表面接枝聚苯乙烯,并利用傅里叶红外光谱(FTIR)、热重分析仪(TGA)对改性前后的纤维素纳米晶体的化学结构和热稳定性进行了研究。测试结果表明,聚苯乙烯可成功地接枝到纤维素纳米晶体的表面; 纤维素纳米晶体的热分解温度由150 ℃上升到220 ℃,改性后纤维素纳米晶体的热稳定性得到提高。采用溶液浇铸法制备聚甲基丙烯酸甲酯/纤维素纳米晶体复合材料(PMMA/CNC),并利用TGA、透光率测试对复合材料热稳定性和透光率进行了研究。结果表明,当温度达到350 ℃时,PMMA/CNC的热分解温度比纯PMMA提高了近150 ℃, CNC的加入量为1%时,复合材料的透光率为89%,接近纯PMMA的透光率(91%)。聚苯乙烯改性纤维素纳米晶体可用于在保持PMMA透明性的前提下更好地改善PMMA复合材料的热稳定性。

Abstract: In order to improve the thermal stability and compatibility with organic materials, cellulose nanocrystals(CNCs)were grafted by polystyrene chains via surface-initiated atom transfer radical polymerization(SI-ATRP). The chemical structure and thermal stability were characterized by the Fourier transform infrared spectroscopy(FTIR)and thermogravimetric analysis(TGA), revealing that polystyrene chains were successfully grafted on the surface of CNCs and the degradation temperature of CNCs increased from 150 ℃ to 220 ℃. Poly(methyl methacrylate)(PMMA)nanocomposites were prepared with the solution casting method and were examined by the TGA and UV-vis spectrophotometer. The remaining rate of PMMA/4%CNC was increased by 100% compared to pure PMMA. The transmittance of the PMMA/1% CNCs approached 89%, which was close to that of the pure PMMA(91%). This research provides a novel method to improve the thermal stability of PMMA/CNC nanocomposite on the premise of remaining the excellent transparency.

中图分类号:

O631

尹园园,田秀枝,朱春波,等. 聚苯乙烯改性纤维素纳米晶体对聚甲基丙烯酸甲酯热稳定性的增强作用[J]. 南京林业大学学报（自然科学版）, 2016, 59(05): 138-142.

YIN Yuanyuan, TIAN Xiuzhi, ZHU Chunbo, JIANG Xue, WANG Hongbo, GAO Weidong. Reinforcement on the thermal stability of poly(methyl methacrylate)of cellulose nanocrystals modified with polystyrene[J].Journal of Nanjing Forestry University (Natural Science Edition), 2016, 59(05): 138-142.DOI: 10.3969/j.issn.1000-2006.2016.05.022.

参考文献

[1] 宋长城.聚甲基丙烯酸甲酯的改性研究[J].内蒙古石油化工,2012(3): 17-18. Song C C. The research of modification of PMMA [J]. Inner Mongolia Petrochemical Industry, 2012(3): 17-18.
[2] 刘继纯,李晴媛,付梦月,等.聚甲基丙烯酸甲酯改性研究进展[J].化工新型材料,2009,37(1):5-7. Liu J C, Li Q Y, Fu M Y, et al. Research advances in the modification of PMMA [J]. New Chemical Materials, 2009, 37(1): 5-7.
[3] 钱家盛,陈晓明,何平笙. PMMA/nano-SiO₂纳米复合材料的制备和表征[J]. 应用化学,2003, 20(12): 1200-1203.Doi:10.3969/j.issn.1000-0518.2003.12.018. Qian J S, Chen X M, He P S. The preparation and characterization of nanocomposites of PMMA/nano-SiO₂[J]. Chinese Journal of Applied Chemistry, 2003, 20(12): 1200-1203.
[4] Qian J S, He P S. Non-isothermal crystallization of HDPE/nano-SiO₂ composite [J]. J Mater Sci, 2003, 38(11): 2299-2304.
[5] 张启卫,章永化,陈守明,等. 聚甲基丙烯酸甲酯/二氧化硅杂化材料制备与性能[J]. 应用化学,2002, 19(9): 874-877.Doi:10.3969/j.issn.1000-0518.2002.09.013. Zhang Q W, Zhang Y H, Chen S M, et al. The preparation and properties of PMMA/SiO₂ hybrid materials [J]. Chinese Journal of Applied Chemistry, 2002, 19(9): 874-877.
[6] 童昕,唐涛,朱宁,等. 利用聚合物乳液合成聚甲基丙烯酸甲酯/二氧化硅纳米杂化材料[J]. 高等学校化学学报,2002, 23(2): 306-309.Doi:10.3321/j.issn.0251-0790.2002.02.022. Tong X, Tang T, Zhu N, et al. The preparation of PMMA/SiO₂ hybrid materials with polymer latex [J]. Chemical Journal of Chinese Universities, 2002,23(2): 306-309.
[7] Choi Y S, Choi M H, Wang K H. Synthesis of exfoliated PMMA/Na-MMT nanocomposites via soap-free emulsion polymerization [J]. Macromolecules, 2001, 34(26): 8978-8985.
[8] Meneghetti P, Qutubuddin S. Synthesis of poly(methyl methacrylate)nanocomposites via emulsion polymerization using a zwitterionic surfactant [J]. Langmuir, 2004(20): 3424-3430.
[9] Huskic^' M, Z^ˇigon M. PMMA/MMT nanocomposites prepared by one-step in situ intercalative solution polymerization [J]. European Polymer Journal, 2007.43(12): 4891-4897.
[10] 任强,李坚,邓健,等. PMMA/蒙脱土纳米复合材料的结构及热性能[J]. 现代塑料加工应用,2009,21(5):52-55.Doi:10.3969/j.issn.1004-3055.2009.05.015. Ren Q, Li J, Deng J, et al. The structure and thermal properties of PMMA/montmorillonite nanocomposites [J]. Modern Plastics Processing and Apllications, 2009, 21(5): 52-55.
[11] 李德强,陈涛,罗石,等.聚甲基丙烯酸甲酯纳米复合材料的制备与性能[J].华东理工大学学报(自然科学版),2009,35(4):559-563. Li D Q, Chen T, Luo S, et al. The preparation and properties of PMMA nanocomposites [J]. Journal of East China University of Science and Technology Natural(Science Edition), 2009, 35(4): 559-563.
[12] 李媛媛,戴红旗.化学法制备纳米微晶纤维素的研究进展[J].南京林业大学学报(自然科学版),2012, 36(5):161-166.Doi:10.3969/j.issn.1000-2006.2012.05.031. Li Y Y, Dai H Q. Preparation of nano-crystalline cellulose by chemical methods [J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2012, 36(5): 161-166.
[13] 何文,尤俊,蒋身学,等. 毛竹纳米纤维素晶体的制备及分析特性[J]. 南京林业大学学报(自然科学版),2013, 37(4): 95-98. He W, You J, Jiang S X, et al. Isolation and characterization analysis of cellulose nanocrystal from moso bamboo [J]. Journal of Nanjing Forestry University(Natural Sciences Edition), 2013, 37(4): 95-98.
[14] Liu H Y, Liu D G,Yao F, et al. Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites [J]. Bioresource Technology, 2010, 101: 5685-5692.
[15] Beck-Candanedo S, Roman M, Gray G D. Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions [J]. Biomacromolecules, 2005, 6(2): 1048-1054.Doi:10.1021/bm049300P.
[16] Majoinen J, Walther A, Mekee J R, et al. Polyelectrolyte brushes grafted from cellulose nanocrystals using Cu-mediated surface-initiated controlled radical polymerization [J]. Biomacromolecules,2011, 12: 2997-3006.Doi:10.1021/bm 200613y.
[17] Lin N, Dufresne A. Physical and/or chemical compatibilization of extruded cellulose nanocrystal reinforced polystyrene nanocomposites [J]. Macromolecules, 2013(46): 5570-5583.Doi:10.1021/ma4010154.

聚苯乙烯改性纤维素纳米晶体对聚甲基丙烯酸甲酯热稳定性的增强作用

Reinforcement on the thermal stability of poly(methyl methacrylate)of cellulose nanocrystals modified with polystyrene

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