南京林业大学学报(自然科学版) ›› 1983, Vol. 7 ›› Issue (03): 97-119.doi: 10.3969/j.jssn.1000-2006.1983.03.012

• 研究论文 • 上一篇    下一篇

云南松松脂化学组成及其蒸馏工艺的研究

安鑫南   

  1. 南京林产工业学院林化系;79级研究生
  • 出版日期:1983-09-18 发布日期:1983-06-18

CHEMICAL COMPOSITION AND DISTILLATING PROCESS OF OLEORESIN FROM PINUS YUNNANENSIS FRANCH

An Xinnan   

  1. Department of Chemical Processing of Forest Products
  • Online:1983-09-18 Published:1983-06-18

摘要: <正> 一、前 言 我国松香生产历史悠久,松脂资源极为丰富。1981年,我国松香产量占世界总产量的三分之一,脂松香的产量已跃居世界首位,年产40万吨以上,但其原料基本上是马尾松松脂。目前,随着经济的发展的需要,必须尽快地开发利用其他松树树种(如云南松、思茅松等)的松脂资源。因而,开展这方面的研究工作就显得十分重要和必要。

Abstract: Chemical compositions of oleoresin from Pinus yunnanensis Franch in different areas have been analyzed by GLC and MS; their distillating processes studied. Results of the investigation can be summarized as follows: The turpentine from P. yunnanensis Franch contains a high percentage of α-pinene (over 86%) and a low content (lower than 2%) of high boiling sesquiturpence. Total fractions of the turpentine come up to thestandard of light turpentine oil. The resin acids in the oleoresin from P. yunnanensis Franch include pimaric acid, sandaracopimaric acid, plustric acid, levopi-maric acid, isopimaric acid, dehydroabietic acid, abietic acid and neoabietic acid. The content of abietic-type resin acids reaches more than 70%. Appropriate processing conditions for distillating oleoresin are: temperature, 160-165°C; duration, about 52 minutos. Qualities of both the tosin and turpentine obtained thereupon are good, but the tosin shows a high crystallizing tendency.