南京林业大学学报(自然科学版) ›› 1988, Vol. 12 ›› Issue (04): 70-74.doi: 10.3969/j.jssn.1000-2006.1988.04.011

• 研究论文 • 上一篇    下一篇

松香胺环氧乙烷缓蚀作用的研究

郑家燊;陈兆喜   

  1. 华中工学院;华中工学院
  • 出版日期:1988-12-18 发布日期:1988-08-18

A STUDY OF THE MECHANISM OF CORROSION-INHIBITING OF ETHOXLATED ROSIN AMINE

Zhen Jiashen Chen Zhaoxi   

  1. Huazhong University of Science and Technology
  • Online:1988-12-18 Published:1988-08-18

摘要: <正>利用失重法测定腐蚀速率,研究松香胺环氧乙烷(RAO)在不同温度、不同浓度下对A_3钢在1N盐酸中缓蚀作用机理。研究结果表明;RAO的缓蚀机理为化学吸附作用;RAO在低温(40℃以下)满足Langmuir吸附,但在高于60℃时不满足Langmuir吸附规律;RAO是一种强烈抑制阴极过程的阴极型缓蚀剂。

Abstract: The mechanism of corrosion-inhibiting action of ethoxylated rosin amine was investigated by measuring the corrosion rates with gravimetric method. The analysis of the kinetics of steel in HC1 solution and the characteristic relationship between the inhibiting efficiency and temperature suggete that chemisorption is the mechanism of inhibiting action of ethoxylated rosin amine (RAO). It has been found that RAO is adsorbed according to Langmuir and non-Langmuir isotherm when the temperature below 40℃ and above 60℃, Polarization measurements indicate that RAO is a strong cathodic inhibitor which inhibits cathodic process of the electrode.