Investigation on the toughening effect of nanoTiO2 to epoxy resin surface size

LI Yuanyuan, DAI Hongqi*, WAN Li

JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2012, Vol. 36 ›› Issue (01) : 105-109.

PDF(2753220 KB)
PDF(2753220 KB)
JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2012, Vol. 36 ›› Issue (01) : 105-109. DOI: 10.3969/j.jssn.1000-2006.2012.01.022

Investigation on the toughening effect of nanoTiO2 to epoxy resin surface size

  • LI Yuanyuan, DAI Hongqi*, WAN Li
Author information +
History +

Abstract

The toughness and mechanical strength of epoxy resin surface size were improved by adding some nanoTiO2 to epoxy resin emulsion dispersed with ultrasonic method. Process parameters were varied systematically with the aim of achieving an optimum dispersion process. The results showed that an optimum dispersion with epoxy resin particle size of 169 μm was achieved when the dispersion time was 30 min, the temperature of epoxy resin was 50 ℃, the ultrasonic amplitude was 100 %, the mass fraction of epoxy resin was 60%, and 3% nanoTiO2 was incorporated. And the opacity, storage modulus and loss factor of modified epoxy resin increased obviously while tend decreased slightly. Compared with unmodified epoxy resin, modified epoxy resin surface sizing agent had a clear positive effect on CD tensile strength, pickstrength and folding strength, where as a little negative influence on stiffness.

Cite this article

Download Citations
LI Yuanyuan, DAI Hongqi*, WAN Li. Investigation on the toughening effect of nanoTiO2 to epoxy resin surface size[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2012, 36(01): 105-109 https://doi.org/10.3969/j.jssn.1000-2006.2012.01.022

References

[1]Jandali M Z, Widmann G. Application Handbook Thermal Analysis[M].陆立明,唐远旺,蔡艺,译.上海:东华大学出版社, 2008.
[2]马妤.新型瓦楞纸增强剂的制备及应用[J].当代化工,2009,38(2):116-119.
[3]Mirmohseni A, Zavareh S.Preparation and characterization of an epoxy nanocomposite toughened by a combination of thermoplastic,layered and particulate nanofillers [J]. Materials and Design,2010,31(6):2699-2706.
[4]曹万荣,符开斌,狄宁宇,等. 无机纳米粒子增韧改性环氧树脂的研究进展[J]. 绝缘材料,2009,42(6):31-35,40.
[5]Carballeira P, Haupert F.Toughening effects of titanium dioxide nanoparticles on TiO2/epoxy resin nanocomposites [J]. Polymer Composites,2010,31(7):1241-1246.
[6]AlTuraif H A.Effect of nano TiO2 particle size on mechanical properties of cured epoxy resin [J]. Progress in Organic Coatings,2010,69(3):241-246.
[7]周金向,黄慧萍,李艳玲,等.环氧树脂的增韧改性新方法[J]. 材料导报,2004,18(11):61-62,69.
[8]Cho J, Joshi M S, Sun C T V. Effect of inclusion size on mechanical properties of polymeric composites with micro and nano particles[J]. Composites Science and Technology,2006,66(13):1941-1952.
[9]Omrania A, Simonb L C, Rostami A A. The effects of alumina nanoparticle on the properties of an epoxy resin system [J]. Materials Chemistry and Physics,2009,114(1):145-150.
[10]Voigt A, Heinrich M, Martin C, et al. Improved properties of epoxy nanocomposites for specific applications in the field of MEMS/NEMS [J]. Microelectronic Engineering,2007,84(5/8):1075-1079.
[11]惠雪梅,张炜,王晓洁.环氧树脂纳米复合材料研究进展 [J].合成树脂及塑料,2003,20(6):62-65.
[12]Nikje M M A,Garmarudi A B,Tehrani Z M,et al.Thermal and mechanical evaluation of epoxy resin composites by synthesis of aminebased coupling agentnano silica complex[J]. Polymerplastics Technology and Engineering,2011,50(6): 646-650.
[13]张绪燕,刘温霞.纳米TiO2的制备及其在造纸工业中的用途[J].纸和造纸,2010,29(5):38-41.
[14]Sauter C, Emin M A, Schuchmann H P, et al. Influence of hydrostatic pressure and sound amplitude on the ultrasound induced dispersion and deagglomeration of nanoparticles [J]. Ultrasonics Sonochemistry, 2008,15(4):517-523.
[15]Bittmann B, Haupert F, Schlarb A K. Ultrasonic dispersion of inorganic nanoparticles in epoxy resin [J].Ultrasonics Sonochemistry, 2009,16(5):622-628.
[16]Vakili Tahami S H, Ranjbar Z, Bastani S. Preparation and stability behavior of the colloidal epoxy1,1iminodi2propanol adducts[J]. Progress in Organic Coatings, 2011,71 (3):234-241.
[17]Chatterjee A, Islam M S.Fabrication and characterization of TiO2epoxy nanocomposite[J]. Materials Science and Engineering:A,2008,487(1/2):574-585.
PDF(2753220 KB)

Accesses

Citation

Detail

Sections
Recommended
The full text is translated into English by AI, aiming to facilitate reading and comprehension. The core content is subject to the explanation in Chinese.

/