JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2021, Vol. 45 ›› Issue (2): 213-219.doi: 10.12302/j.issn.1000-2006.201912036
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ZHANG Xingzheng(), LI Xinyu, CHENG Yunqing, LIU Jianfeng*()
Received:
2019-12-20
Accepted:
2020-11-20
Online:
2021-03-30
Published:
2021-04-09
Contact:
LIU Jianfeng
E-mail:zxz20051986@163.com;jianfengliu1976@163.com
CLC Number:
ZHANG Xingzheng, LI Xinyu, CHENG Yunqing, LIU Jianfeng. GC-MS detection of pesticide residues in the hazelnut and dietary risk assessment[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY, 2021, 45(2): 213-219.
Table 1
The CAS number, LOQ, recovery rate and LOD of 19 pesticide standards"
杀虫剂类型 type of pesticide | 杀虫剂 pesticide | CAS号 CAS No. | 定量限/ (μg·kg-1) LOQ | 回收率/% recovery rate | 检出限/ (μg·kg-1) LOD |
---|---|---|---|---|---|
有机磷类杀虫剂 organophosphates | 敌敌畏dichlorvos | 62-73-7 | 2.4 | 89.1~93.2 | 0.7 |
乐果dimethoate | 60-51-5 | 1.5 | 82.3~108.2 | 0.4 | |
二嗪磷diazinon | 333-41-5 | 0.4 | 82.6~93.0 | 0.2 | |
杀螟硫磷fenitrothion | 122-14-5 | 6.1 | 92.5~98.4 | 1.8 | |
马拉硫磷malathion | 121-75-5 | 3.0 | 93.1~96.0 | 0.9 | |
毒死蜱chlorpyrifos | 2921-88-2 | 3.5 | 95.7~96.5 | 1.0 | |
对硫磷parathion | 56-38-2 | 5.0 | 86.8~93.1 | 1.5 | |
丙溴磷profenofos | 41198-08-7 | 11.6 | 97.6~103.1 | 3.5 | |
哒螨灵pyridaben | 96489-71-3 | 0.2 | 74.3~90.8 | 0.1 | |
有机氯类杀虫剂 organochlorines | 六六六lindane | 58-89-9 | 11.4 | 85.5~105.7 | 3.3 |
五氯硝基苯pentachlor | 82-68-8 | 10.6 | 91.3~110.1 | 3.1 | |
除虫菊酯类杀虫剂 pyrethroids | 氟氰戊菊酯flucythrinate | 70124-77-5 | 10.9 | 101.9~113.1 | 3.2 |
氟胺氰菊酯tau-fluvalinate | 102851-06-9 | 8.9 | 103.1~115.8 | 2.8 | |
联苯菊酯bifenthrin | 82657-04-3 | 0.2 | 79.9~86.5 | 0.1 | |
甲氰菊酯fenpropathrin | 64257-84-7 | 1.9 | 82.3~90.4 | 0.6 | |
氯氟氰菊酯cyhalothrin | 91465-08-6 | 10.9 | 80.3~95.2 | 3.4 | |
氟氯氰菊酯cyfluthrin | 68359-37-5 | 17.5 | 88.9~99.1 | 5.3 | |
氯氰菊酯cypermethrin | 52315-07-8 | 37.0 | 93.2~106.0 | 11.1 | |
醚菊酯ethofenprox | 80844-07-1 | 11.4 | 100.8~113.3 | 3.3 |
Table 2
The analysis of OPs residues in chemical controlled hazel orchards mg/kg"
杀虫剂 pesticide | 果仁 kernel | 果壳 shell | 叶片 leaf | 土壤 soil | 最高残留限量[ (中国) MRL(China) |
---|---|---|---|---|---|
敌敌畏dichlorvos | n.d.~1.140 3 | n.d.~1.443 6 | n.d.~2.624 7 | n.d.~2.726 2 | 0.20* |
乐果dimethoate | n.d.~0.041 0 | n.d.~0.735 8 | n.d. | n.d.~1.735 1 | 0.50* |
二嗪磷diazinon | n.d.~0.008 8 | n.d.~0.001 9 | n.d. | n.d.~0.119 5 | 0.01 |
杀螟硫磷fenitrothion | n.d.~0.905 2 | n.d.~2.020 8 | n.d. | n.d.~1.429 4 | 0.50* |
马拉硫磷malathion | n.d.~0.004 1 | n.d.~0.001 6 | n.d.~1.015 7 | n.d.~2.654 8 | 0.50* |
毒死蜱chlorpyrifos | n.d.~0.000 1 | n.d.~0.146 9 | n.d. | n.d. | 0.50* |
对硫磷parathion | n.d.~0.000 3 | n.d.~0.000 5 | n.d. | n.d. | 0.01* |
丙溴磷profenofos | n.d.~0.025 7 | n.d.~0.024 8 | n.d. | n.d.~2.017 4 | 0.05* |
哒螨灵pyridaben | n.d. | n.d. | n.d. | n.d. | 2.00* |
Table 4
The analysis of PYs residues in chemical controlled hazel orchardsmg/kg"
杀虫剂 pesticide | 果仁 kernel | 果壳 shell | 叶片 leaf | 土壤 soil | 最高残留限量(中国) MRL(China) |
---|---|---|---|---|---|
氟氰戊菊酯flucythrinate | n.d.~1.247 6 | n.d.~1.741 5 | n.d.~2.165 6 | n.d.~1.547 7 | 0.50* |
氟胺氰菊酯tau-fluvalinate | n.d. | n.d. | n.d. | n.d. | 0.50* |
联苯菊酯bifenthrin | n.d.~0.000 4 | n.d.~0.000 2 | n.d. | n.d. | 0.05* |
甲氰菊酯fenpropathrin | n.d. | n.d. | n.d. | n.d. | 5.00* |
氯氟氰菊酯cyhalothrin | n.d.~1.469 2 | n.d.~2.085 2 | n.d. | n.d.-2.063 2 | 0.01 |
氟氯氰菊酯cyfluthrin | n.d. | n.d. | n.d. | n.d. | 0.20* |
氯氰菊酯cypermethrin | n.d.~0.018 0 | n.d.~2.683 0 | n.d.~3.107 2 | n.d.~3.244 2 | 0.05 |
醚菊酯ethofenprox | n.d. | n.d.~0.001 3 | n.d. | n.d.~0.079 3 | 0.20* |
Table 5
The short-term and long-term risks due to average daily intake of pesticides through nut consumption"
杀虫剂 pesticide | 短期风险 short-term risk | 长期风险 long-term risk | |||||
---|---|---|---|---|---|---|---|
ESTI/ (mg·kg-1·d-1) | ARfD/ (mg·kg-1·d-1) | aHI/% | EDI/ (mg·kg-1·d-1) | ADI/ (mg·kg-1·d-1) | HQ/% | ||
敌敌畏dichlorvos | 7.13×10-4 | 0.100 | 0.71 | 2.20×10-4 | 0.004 | 5.50 | |
乐果dimethoate | 1.39×10-5 | 0.020 | 0.07 | 1.39×10-5 | 0.002 | 0.69 | |
二嗪磷diazinon | 2.93×10-6 | 0.030 | 0.01 | 1.52×10-6 | 0.005 | 0.03 | |
杀螟硫磷fenitrothion | 3.02×10-4 | 0.040 | 0.75 | 1.04×10-4 | 0.006 | 1.73 | |
马拉硫磷malathion | 1.36×10-6 | 2.000 | 0.00 | 9.48×10-7 | 0.300 | 0.00 | |
毒死蜱chlorpyrifos | 3.83×10-8 | 0.100 | 0.00 | 3.83×10-8 | 0.010 | 0.00 | |
对硫磷parathion | 1.08×10-7 | 0.010 | 0.00 | 1.08×10-7 | 0.004 | 0.00 | |
丙溴磷profenofos | 8.58×10-6 | 1.000 | 0.00 | 8.58×10-6 | 0.030 | 0.03 | |
哒螨灵pyridaben | / | / | / | / | 0.010 | / | |
六六六lindane | 7.75×10-6 | / | / | 4.02×10-6 | 0.005 | 0.08 | |
五氯硝基苯pentachlor | / | / | / | / | 0.010 | / | |
氟氰戊菊酯flucythrinate | 4.16×10-4 | / | / | 1.16×10-4 | 0.020 | 0.58 | |
氟胺氰菊酯tau-fluvalinate | / | / | / | / | 0.005 | / | |
联苯菊酯bifenthrin | 1.35×10-7 | 0.010 | 0.00 | 1.35×10-7 | 0.01 | 0.00 | |
甲氰菊酯fenpropathrin | / | 0.030 | / | / | 0.030 | / | |
氯氟氰菊酯cyhalothrin | 4.90×10-4 | 0.020 | 2.45 | 2.93×10-4 | 0.020 | 1.47 | |
氟氯氰菊酯cyfluthrin | / | 0.040 | / | / | 0.040 | / | |
氯氰菊酯cypermethrin | 6.00×10-6 | 0.040 | 0.020 | 4.52×10-6 | 0.020 | 0.02 | |
醚菊酯ethofenprox | / | / | / | / | 0.030 | / |
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