Construction of hydrophobic nano-TiO2 on wood surface and analysis of its anti-photodiscoloration performance

CHANG Huanjun, LIU Sichen, WANG Xiaoqing, LIU Junliang

JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2015, Vol. 39 ›› Issue (04) : 116-120.

PDF(1901762 KB)
PDF(1901762 KB)
JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2015, Vol. 39 ›› Issue (04) : 116-120. DOI: 10.3969/j.issn.1000-2006.2015.04.020

Construction of hydrophobic nano-TiO2 on wood surface and analysis of its anti-photodiscoloration performance

  • CHANG Huanjun1,2, LIU Sichen1,3, WANG Xiaoqing1,2*, LIU Junliang1,2
Author information +
History +

Abstract

Wood surface was modified by nona-TiO2 coating via sol-gel process at room temperature, followed by low surface energy treatment with stearic acid in order to transform the wood surface from hydrophilic to hydrophobic. In the meanwhile, the photostability of wood was also improved due to excellent UV-shielding property of nano-TiO2. The surface morphology, structure and chemistry of the treated wood were studied by field emission scanning electron microscopy(FE-SEM), energy dispersive X-ray analysis(EDX), and fourier transform infrared spectroscopy(FTIR). The hydrophobicity and anti-photodiscoloration performance of treated wood were tested. The results showed that the TiO2 nanoparticles were successfully introduced onto the wood surface, and the long-chain alkyl groups of stearic acid were grafted to provide hydrophobicity. The water contact angles of the treated wood were improved remarkably to approximately 130° displaying high hydrophobicity. The nano-TiO2 films also improved the anti-photodiscoloration performance of wood remarkably. The overall color change(ΔE*)of the wood samples treated with 5% TiO2 sol, was only 45% of the corresponding value of the control samples after 120 h artificial accelerated weathering.

Cite this article

Download Citations
CHANG Huanjun, LIU Sichen, WANG Xiaoqing, LIU Junliang. Construction of hydrophobic nano-TiO2 on wood surface and analysis of its anti-photodiscoloration performance[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2015, 39(04): 116-120 https://doi.org/10.3969/j.issn.1000-2006.2015.04.020

References

[1] 李坚, 邱坚. 纳米科技及其在木材科学中的应用前景(Ⅱ)—纳米复合材料的结构、性能和应用[J]. 东北林业大学学报, 2003, 31(2): 1-3.Li J, Qiu J. The application prospects of nano-ST in the wood science(Ⅱ): nanocomposites material structure, properties and application [J]. Journal of Northeast Forestry University, 2003, 31(2): 1-3.
[2] 邱坚, 李坚. 纳米科技及其在木材科学中的应用前景(Ⅰ)—纳米材料的概括、制备和应用前景[J]. 东北林业大学学报, 2003, 31(1): 1-4.Qiu J, Li J. The application prospects of nano-ST in the wood science(Ⅰ): nano material survey, preparation and application prospects [J]. Journal of Northeast Forestry University, 2003, 31(1).1-4.
[3] Saka S, Utno T. Several SiO2 wood-inorganic composites and their fire-resisting properties [J]. Wood Science and Technology, 1997, 31(6): 457-466.
[4] Donath S, Militz H, Mai C. Wood modification with alkoxysilanes [J]. Wood Science and Technology, 2004, 38(7): 555-566.
[5] Mahltig B, Swaboda B, Roessler A, et al. Functionalising wood by nanosol application [J]. Journal of Materials Chemistry, 2008, 18: 3180-3192.
[6] 江泽慧, 孙丰玻, 余雁, 等. 竹材的纳米TiO2改性及防光变色性能[J]. 林业科学, 2010, 46(2): 116-121.Jiang Z H, Sun F B, Yu Y, et al. Modification of nano TiO2 on bamboo and its anti-photodiscoloration performance [J]. Scientia Silvae Sinicae, 2010, 46(2): 116-121.
[7] 宋烨, 吴义强, 余雁. 二氧化钛对竹材颜色稳定性和防霉性能的影响[J]. 竹子研究会刊, 2009, 28(1): 30-34.Song Y, Wu Y Q, Yu Y. Effect of titanium dioxide on color stability and mildewproof properties of bamboo [J]. Journal of Bamboo Research, 2009, 28(1): 30-34.
[8] Sun Q F, Yu H P, Liu Y X, et al.Improvement of water resistance and dimensional stability of wood through titanium dioxide coating [J]. Holzforschung, 2010, 64(6): 757-761.
[9] Sun Q F, Lu Y, Liu Y X. Growth of hydrophobic TiO2 on wood surface using a hydrothermal method [J]. Journal of Materials Science, 2011, 46(24): 7706-7712.
[10] Pandey K K. A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy [J]. Journal of Applied Polymer Science, 1999, 71(12):1969-1975.
[11] Gao L J, He J H. Surface hydrophobic co-modification of hollow silica nanoparticles toward large-area transparent superhydrophobic coatings [J]. Journal of Colloid and Interface Science, 2013, 396: 152-159.
[12] Nishino T, Meguro M, Nakamae, et al. The lowest surface freeenergy based on -CF3 alignment [J]. Langmuir, 1999, 15: 4321-4323.
[13] Abidi N, Hequet E, Tarimals S, et al. Cotton fabric surfacemodification for improved UV radiation protection using sol-gel process [J]. Journal of Applied Polymer Science, 2007, 104(1):111-117.
[14] Xue C H, Jia S T, Chen H Z, et al.Superhydrophobic cotton fabrics prepared by sol-gel coating of TiO2 and surface hydrophobization [J]. Science and Technology of Advanced Materials, 2008, 9(3): 1-5.
[15] Nelson K, Deng Y.Effect of polycrystalline structure of TiO2 particles on the light scattering efficiency [J]. Journal of Colloid and Interface Science, 2008, 319: 130-139.
PDF(1901762 KB)

Accesses

Citation

Detail

Sections
Recommended
The full text is translated into English by AI, aiming to facilitate reading and comprehension. The core content is subject to the explanation in Chinese.

/