Investigation on preparation and properties of biodiesel from rapeseed oil with high content of erucic acids

QI Peipei, WANG Fei

Journal of Nanjing Forestry University (Natural Sciences Edition) ›› 2009, Vol. 33 ›› Issue (01) : 87-91.

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Journal of Nanjing Forestry University (Natural Sciences Edition) ›› 2009, Vol. 33 ›› Issue (01) : 87-91. DOI: 10.3969/j.jssn.1000-2006.2009.01.018

Investigation on preparation and properties of biodiesel from rapeseed oil with high content of erucic acids

  • QI Peipei, WANG Fei
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Abstract

The preparation and properties of biodiesel from rapeseed oil containing high content of erucic acids were systematically investigated in this paper. The composition of obtained biodiesel was analyzed with gas chromatographymass spectrometry (GCMS). The results showed that the components of the resulting biodiesel were the methyl esters of erucic acid, oleic acid, linoleic acid and eicosenoic acid. The main factors affecting the transesterification of rapeseed iol, such as molar ratio of methanol to oil, reaction temperature and catalyst (potassium hydroxide) dosage, were also discussed. The suitable conditions for biodiesel preparation were molar ratio of methanol to oil 5∶1, reaction temperature 60℃ and catalyst dosage 1%. Under the conditions the yield of fatty acid methyl ester was 923%.The properties of the biodiesel such as cetane value, caloric value, acid value, viscosity and flash point were tested according to the standard methods. It was indicated that the biodiesel could meet the requirements as fuel, even prepared from rapeseed oil containing high content of erucic acids.

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QI Peipei, WANG Fei. Investigation on preparation and properties of biodiesel from rapeseed oil with high content of erucic acids[J]. Journal of Nanjing Forestry University (Natural Sciences Edition). 2009, 33(01): 87-91 https://doi.org/10.3969/j.jssn.1000-2006.2009.01.018

References

[1]Martini N, Schell S. Plant oil as fuels: present state of future developments [J]. Proceedings of the Symposium,1997 (2):1618.
[2]Ma F R, Milford A H. Biodiesel production: a review [J]. Bioresource Technology,1999,70:115.
[3]Klass D L. Biomass for Renewable Energy, Fuels, and Chemicals [M]. New York: Academic Press,1998.
[4]Sprules F J, Price D. Production of fatty esters: US, 2366494[P].1950-03-09.
[5]Goering C E. Fuel properties of eleven oils [J]. Trans ASAE, 1982, 25: 14721483.
[6]Ayhan D. Biodiesel from vegetable oils via transesterification in supercritical methanol [J]. Energy conversion and management, 2002, 43: 23492356.
[7]Schwab A W, Bagby M O, Freedman B. Preparation and properties of diesel fuels from vegetable oils [J]. Fuel, 1987, 66: 13721378.
[8]Bradshaw G B, Meuly W C. Preparation of detergents:US, 2360844[P].1994-10-24.
[9]Freedman B, Butterfield R O, Pryde E H. Transesterification kinetics of soybean oil [J]. JAOCS, 1986, 63:13751380.
[10]Smith M K. Process of producing esters: US, 2444486[P]. 1949-01-25.
[11]Freedman B, Pryde E H, Mount T L. Variables affecting the yields of fatty esters from transesterified vegetable oils [ J].JAOCS, 1984, 61:16381643.
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