Synthesis and ultraviolet absorption characteristics of 7-arylidene-isolongifolanene

doi:10.3969/j.issn.1000-2006.2016.02.015

RUI Jian,XU Xu^{1, 2, 4},YANG Yiqing,HUANG Jianfeng,WANG Shifa^1,3,4*

JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2016, Vol. 40 ›› Issue (02) : 88-94.

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JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2016, Vol. 40 ›› Issue (02) : 88-94. DOI: 10.3969/j.issn.1000-2006.2016.02.015

Synthesis and ultraviolet absorption characteristics of 7-arylidene-isolongifolanene

RUI Jian¹,XU Xu^{1, 2, 4},YANG Yiqing³,HUANG Jianfeng¹,WANG Shifa^1,3,4*

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Abstract

A series of 7-arylidene-isolongifolanone a—j were synthesized by condensation of isolongifolanone with aromatic aldehydes including 4-bromobenzaldehyde, 4-fluorobenzaldehyde, 3-nitrobenzaldehyde, 2,4-dichlorobenzaldehyde under catalyzation of potassium tert-butoxide. The structures of compounds a—j were identified by means of ¹H NMR, ¹³C NMR, GC-MS and FT-IR, and their ultraviolet absorption characteristics as well as light stabilities were also investigated. The results showed that compounds a, b, c, d and j exhibited good absorbency as the medium-wave ultraviolet(UVB)type absorbents,and compounds e, f, g, h and i had both functions as long-wave ultraviolet(UVA)and UVB absorbents. The light stability sequence of those compounds was h>g>e>c>a>d>b>f>i>j. The UV absorption intensity was d>i>e>h>g>f>b>c>j>a.

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RUI Jian,XU Xu^{1, 2, 4},YANG Yiqing,HUANG Jianfeng,WANG Shifa^1,3,4*. Synthesis and ultraviolet absorption characteristics of 7-arylidene-isolongifolanene[J]. JOURNAL OF NANJING FORESTRY UNIVERSITY. 2016, 40(02): 88-94 https://doi.org/10.3969/j.issn.1000-2006.2016.02.015

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