JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 1986, Vol. 10 ›› Issue (04): 65-77.doi: 10.3969/j.jssn.1000-2006.1986.04.009

Previous Articles     Next Articles

ESTERIFICATION KINETICS OF AN ADDUCT OF ETHYL PIMAEICATE AND MALEIC ANHYDRIDE WITH ETHYL ALCOHOL

Li Weihui, Huang Xiba & Zhang Jinkang   

  1. Department of Forest Products Chemistry and Engineering
  • Online:1986-12-18 Published:1986-08-18

Abstract: Kineties of catalytic esterification of alcohol with an adduct of ethyl pima ricate and maleic anhydride have been investigated using anhydrous aluminium chloride as catalyst. Effects of variables such as temperature, concentrations of reactants and catalyst have been studied and a correlation of second-step kinetics has been proposedwhere B stands for ethyl alcohol and A represents the adduct of ethyl pimaricate and moneethyl maleicate. Prior to the investigation of the kinetics, a pure adduct of ethyl pimaricate and maleic anhydride were prepared and its melting point, content of anhydride and gas chromatogram, infrered spectum, mass spectum given.