JOURNAL OF NANJING FORESTRY UNIVERSITY ›› 2007, Vol. 31 ›› Issue (03): 95-98.doi: 10.3969/j.jssn.1000-2006.2007.03.020

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Amine Addition Reaction of C60with Dehydroabietylamine Catalyzed by AICl3

GAO Jian1, LIN Zhong-xiang1*, DENG Hui-min2   

  1. 1. College of Chemica! Engineering Nanjing Forestry University, Nanjing 210037, China; 2. Instrumental Apalysis and Research Center, Sun Yat sen University, Guangzhou 510275, China
  • Online:2007-06-18 Published:2007-06-18

Abstract: In order to obtain Friedel-Crafts adduct of C60 with dehydroabietylamine, the reaction of C60 with dehydroabietylamine was carried out in the presence of AlCl2 in chlorobcn zene at 130 C for 3 d in the dark. The derivatives of C60 were isolated by silica column chromatography and characterized by FT-1R, 13C NMR, 1H NMR, ESI-MS. The results showed that arnine addition reaction between C60 and dehydroabietylamine took place instead of Friedel-Crafts reaction, and a mono-adduct of C60 and dehydroabietylamine obtained as the main product. A new synthesis method of C60 and amino was provided.

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