Research on the alkylation modification of cellulose nanofiber 
separated from moso bamboo

doi:10.3969/j.issn.1000-2006.2016.02.024

Research on the alkylation modification of cellulose nanofiber separated from moso bamboo

HE Wen, LI Jiping, JIN Hui, Tian Jiaxi

Journal of Nanjing Forestry University (Natural Sciences Edition） ›› 2016, Vol. 40 ›› Issue (02) : 144-148.

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Journal of Nanjing Forestry University (Natural Sciences Edition） ›› 2016, Vol. 40 ›› Issue (02) : 144-148. DOI: 10.3969/j.issn.1000-2006.2016.02.024

Research on the alkylation modification of cellulose nanofiber separated from moso bamboo

HE Wen¹, LI Jiping², JIN Hui², Tian Jiaxi²

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Abstract

In order to improve the dispersity and interfacial bonding in the nonpolar polymers, cellulose nanofiber(CNF)isolated from moso bamboo were modified with(3-Aminopropyl)triethoxysilane(KH-570)dissolved in the ethanol and toluene, respectively. The properties of the modified CNF were measured by FTIR, X-ray diffractometer(XRD), energy dispersive analysis of X-rays(EDAX)and X-ray photoelectron spectrometer(XPS). The results showed that hydroxyl group in cellulose nanofibers reacted with the Si-OH in KH-570, and the cellulose crystal structure remained unchangeable. However, the relative crystallinity of CNF decreased. The amount of C and O atoms on the CNF surface decreased with the alkylation modification. The results also showed that modified CNF performed better when KH-570 were dissolved in ethanol than in toluene.

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HE Wen, LI Jiping, JIN Hui, Tian Jiaxi. Research on the alkylation modification of cellulose nanofiber separated from moso bamboo[J]. Journal of Nanjing Forestry University (Natural Sciences Edition）. 2016, 40(02): 144-148 https://doi.org/10.3969/j.issn.1000-2006.2016.02.024

References

[1] 何文,尤骏,蒋身学,等.毛竹纳米纤维素晶体的制备及特征分析[J].南京林业大学学报(自然科学版),2013,37(4):95-98. He W, You J, Jiang S X, et al. The characeristics and isolation of Moso-bamboo cellulose nanocrystal[J]. Journal of Nanjing Forestry University(Natural Sciences Edition),2013,37(4):95-98.
[2] He W, Jiang S X, Zhang Q S, et al. Isolation and characterization of cellulose nanofibers from Bambusa rigida[J]. BioResources,2013,8(4):5678-5689.
[3] 曲萍,王璇,白浩龙,等. 纳米纤维素表面烷基化特性的研究[J].北京林业大学学报,2014,36(1):121-125. Qu P,Wang X,Bai H L, et al. Surface alkylation characters of cellulose nanofibrils[J]. Journal of Beijing Forestry University, 2014,36(1):121-125.
[4] Qu P, Zhang X L, Zhou Y T, et a1. Biomimetic synthesis of hydroxyapatite on cellulose nanofibrils and its application[J]. Science of Advanced Materials, 2012,4(2):187-192.
[5] Qu P, Zhou Y T, Zhang X L, et al. Surface modification of cellulose nanofibrils for poly(lactic acid)composite application [J]. Journal of Applied Polymer Science, 2012, 125:3084-3091.
[6] Rehman I, Bonfield W. Characterization of hydroxyapatite and carbonated apatite by photo acoustic FTIR spectroscopy [J]. Journal of Materials Science-Materials in Medicine, 1997,8(1):1-4.
[7] Martens W, Frost R L. An infrared spectroscopic study of the basic copper phosphate minerals: Cornetite, libethenite, and pseudomalachite [J]. American Mineralogist, 2003,88(1):37-46.
[8] Gousse C, Chanzy H, Excoffier G, et al. Stable suspensions of partially silylated cellulose whiskers dispersed in organic solvents [J]. Polymer, 2002, 43(9):2645-2651.
[9] 林剑,赵广杰,孟令萱,等. 利用X射线衍射技术与红外光谱分析真菌侵蚀的木材[J]. 光谱学与光谱分析,2010, 30(6): 1674-1677. Lin J, Zhao G J, Meng L X, et al. Analysis of decayed wood by fungi with X-ray diffractometry and fourrier transform infrared spectroscopy[J].Spectroscopy and Spectral Analysis, 2010,30(6):1674-1677.
[10] 刘世宏,王当憨,潘承璜. X射线光电子能谱分析[M].北京:科学出版社,1988:46-49.
[11] 卢永泉,邓振华.实用红外光谱解析[M].北京:电子工业出版社,1989:143-152.
[12] 胡福增.材料表面与界面[M].上海:华东理工大学出版社,2008:150-156.
[13] 范子千,袁晔,沈青.纳米纤维素研究及应用进展Ⅱ[J]. 高分子通报,2010, 25(3):40-60. Fan Z Q, Yuan Y, Shen Q. The research and development of cellulose nanofibrils II[J]. Polymer Bulletin, 2010,25(3):40-60.
[14] 唐焕威,张力平,李帅,等.聚醚砜/微纳纤维素复合膜材料的光谱表征与性能研究[J].光谱学与光谱分析, 2010, 30(3): 630-634. Tang H W, Zhang L P, Li S, et al. Study on spectroscopic characterization and properties of PES/Micro-nano cellulose composite membrane material[J]. Spectroscopy and Spectral Analysis,2010,30(3):630-634.
[15] 杨万泰.聚合物材料表征与测试[M]. 北京:中国轻工业出版社,2008:13-15.

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